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The coordination chemistry of saturated molecules

Bercaw, John E. and Labinger, Jay A. (2007) The coordination chemistry of saturated molecules. Proceedings of the National Academy of Sciences of the United States of America, 104 (17). pp. 6899-6900. ISSN 0027-8424. PMCID PMC1855396. http://resolver.caltech.edu/CaltechAUTHORS:BERpnas07

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Abstract

Our understanding of bonding in transition metal complexes, as well as our ability to use that understanding in the synthesis and application of new species, has evolved over the last 100 years; and in some sense this special feature on the coordination chemistry of saturated molecules may be considered to represent its culmination. The nature of complexes between transition metal ions and neutral molecules such as ammonia was first correctly described by Werner around the beginning of the 20th century. Interpretations in terms of electronic bonding theories followed soon after. The key feature, of course, is the availability of a low-energy filled "lone pair" orbital available for donation to a vacant orbital on the electron-accepting metal ion.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1855396/PubMed CentralArticle
ORCID:
AuthorORCID
Labinger, Jay A.0000-0002-1942-9232
Additional Information:© 2007 by the National Academy of Sciences. Published online before print as 10.1073/pnas.0700902104.
Issue or Number:17
PubMed Central ID:PMC1855396
Record Number:CaltechAUTHORS:BERpnas07
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:BERpnas07
Alternative URL:http://dx.doi.org/10.1073/pnas.0700902104
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:9103
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:29 Oct 2007
Last Modified:21 Sep 2017 21:50

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