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Swimming to Stability: Structural and Dynamical Control via Active Doping

Omar, Ahmad K. and Wu, Yanze and Wang, Zhen-Gang and Brady, John F. (2019) Swimming to Stability: Structural and Dynamical Control via Active Doping. ACS Nano, 13 (1). pp. 560-572. ISSN 1936-0851. doi:10.1021/acsnano.8b07421.

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External fields can decidedly alter the free energy landscape of soft materials and can be exploited as a powerful tool for the assembly of targeted nanostructures and colloidal materials. Here, we use computer simulations to demonstrate that nonequilibrium internal fields or forces—forces that are generated by driven components within a system—in the form of active particles can precisely modulate the dynamical free energy landscape of a model soft material, a colloidal gel. Embedding a small fraction of active particles within a gel can provide a unique pathway for the dynamically frustrated network to circumvent the kinetic barriers associated with reaching a lower free energy state through thermal fluctuations alone. Moreover, by carefully tuning the active particle properties (the propulsive swim force and persistence length) in comparison to those of the gel, the active particles may induce depletion-like forces between the constituent particles of the gel despite there being no geometric size asymmetry between the particles. These resulting forces can rapidly push the system toward disparate regions of phase space. Intriguingly, the state of the material can be altered by tuning macroscopic transport properties such as the solvent viscosity. Our findings highlight the potential wide-ranging structural and kinetic control facilitated by varying the dynamical properties of a remarkably small fraction of driven particles embedded in a host material.

Item Type:Article
Related URLs:
URLURL TypeDescription Paper
Omar, Ahmad K.0000-0002-6404-7612
Wang, Zhen-Gang0000-0002-3361-6114
Brady, John F.0000-0001-5817-9128
Additional Information:© 2018 American Chemical Society. Received: September 28, 2018; Accepted: December 28, 2018; Published: December 28, 2018. A.K.O. acknowledges support by the National Science Foundation Graduate Research Fellowship under Grant No. DGE-1144469 and an HHMI Gilliam Fellowship. Y.W. acknowledges the Caltech SURF program and support by the Talent Training Program in Basic Science of the Ministry of Education of the People’s Republic of China. J.F.B. acknowledges support by the National Science Foundation under Grant No. CBET-1437570. The authors declare no competing financial interest.
Funding AgencyGrant Number
NSF Graduate Research FellowshipDGE-1144469
Howard Hughes Medical Institute (HHMI)UNSPECIFIED
Caltech Summer Undergraduate Research Fellowship (SURF)UNSPECIFIED
Ministry of Education (China)UNSPECIFIED
Subject Keywords:dynamic assembly, active matter, colloidal gel, depletion, Brownian dynamics
Issue or Number:1
Record Number:CaltechAUTHORS:20190102-092234094
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Official Citation:Swimming to Stability: Structural and Dynamical Control via Active Doping. Ahmad K. Omar, Yanze Wu, Zhen-Gang Wang, and John F. Brady. ACS Nano 2019 13 (1), 560-572. DOI: 10.1021/acsnano.8b07421
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:91978
Deposited By: George Porter
Deposited On:02 Jan 2019 18:51
Last Modified:16 Nov 2021 03:46

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