CaltechAUTHORS
  A Caltech Library Service

Multiple Stages of Carbonation and Element Redistribution during Formation of Ultramafic-Hosted Magnesite in Neoproterozoic Ophiolites of the Arabian-Nubian Shield, Egypt

Azer, Mokhles K. and Gahlan, Hisham A. and Asimow, Paul D. and Mubarak, Heba S. and Al-Kahtany, Khaled M. (2019) Multiple Stages of Carbonation and Element Redistribution during Formation of Ultramafic-Hosted Magnesite in Neoproterozoic Ophiolites of the Arabian-Nubian Shield, Egypt. Journal of Geology, 127 (1). pp. 81-107. ISSN 0022-1376. http://resolver.caltech.edu/CaltechAUTHORS:20190117-083853716

[img] Archive (ZIP) (Tables S1–S11) - Supplemental Material
See Usage Policy.

185Kb

Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20190117-083853716

Abstract

We present a study of the serpentinized peridotites of the Ghadir-Mohagar-Ambaut area, Egypt. They represent the mantle section of a dismembered ophiolite, tectonically emplaced over a volcanosedimentary succession of island arc assemblages. The serpentinites are variably metamorphosed from greenschist to lower-amphibolite facies, metasomatized, and altered, including development of talc-carbonate and quartz-carbonate rocks, especially along shear zones and fault planes. Nevertheless, some samples contain relics of primary chromian spinel, olivine, and pyroxenes. Relict textures and whole-rock compositions (Mg#[molar Mg/(Mg+Fe^(2+))]=0.92–0.93, with low Al_2O_3 and CaO contents) both suggest harzburgite protoliths. The high Mg# and Ni contents of relict olivine and the high Cr# (molar Cr/(Cr+Al)molar Cr/(Cr+Al)) of fresh chromian spinel cores indicate that the protoliths experienced high degrees of partial melt extraction (∼34%–39%), well beyond the limit for exhaustion of clinopyroxene from the residue and consistent with formation in a forearc suprasubduction zone environment. The serpentinized ultramafic rocks in the study area are divided into massive serpentinite, serpentinite-hosted magnesite masses, and magnesite-filled veins. The carbonation and formation of magnesite ores took place through two metasomatic stages; the first is represented by the magnesite masses and associated with deep-seated metasomatism and alteration during serpentinization, whereas the second, vein-forming stage postdates serpentinization and occurred during obduction of the ophiolite. The differences in chemical composition between massive serpentinite and serpentinite-hosted magnesite masses suggest leaching of some elements and enrichment of others during carbonation; MgO, Cr, and Ni are depleted, whereas Fe_2O_3, CaO, MnO, Nb, Ba, Cu, Pb, Sr, and Zn are enriched in the serpentinite-hosted magnesite masses, relative to the host massive serpentinite.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1086/700652DOIArticle
ORCID:
AuthorORCID
Asimow, Paul D.0000-0001-6025-8925
Additional Information:© 2018 by The University of Chicago. Manuscript received April 14, 2018; accepted September 13, 2018; electronically published December 7, 2018. We acknowledge the logistical support provided by the Geological Sciences Department–National Research Centre, Egypt. P. D. Asimow acknowledges support from the US National Science Foundation, award EAR-1551433. We extend our appreciation to the Deanship of Scientific Research, King Saud University, for supporting this work through research group RG-1436-036. Special thanks to C. Ma for his help with the microprobe analyses.
Funders:
Funding AgencyGrant Number
National Research Centre (Egypt)UNSPECIFIED
NSFEAR-1551433
King Saud UniversityRG-1436-036
Record Number:CaltechAUTHORS:20190117-083853716
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20190117-083853716
Official Citation:Multiple Stages of Carbonation and Element Redistribution during Formation of Ultramafic-Hosted Magnesite in Neoproterozoic Ophiolites of the Arabian-Nubian Shield, Egypt Mokhles K. Azer, Hisham A. Gahlan, Paul D. Asimow, Heba S. Mubarak, and Khaled M. Al-Kahtany The Journal of Geology 2019 127:1, 81-107, doi: 10.1086/700652
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:92335
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:22 Jan 2019 22:46
Last Modified:22 Jan 2019 22:46

Repository Staff Only: item control page