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The Hydration of Unsaturated Compounds. I. The Hydration Rate of Isobutene in Dilute Nitric Acid

Lucas, Howard J. and Eberz, W. Ferdinand (1934) The Hydration of Unsaturated Compounds. I. The Hydration Rate of Isobutene in Dilute Nitric Acid. Journal of the American Chemical Society, 56 (2). pp. 460-464. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20190211-144058865

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Abstract

The hydration of isobutene has been observed by others. Butlerow found that dilute nitric acid (10% ?) or very dilute sulfuric acid brings about the change at the ordinary temperature and Miklaschewsky found that a 5-10% solution of formic, acetic or oxalic acid brings about the hydration, not only of isobutene but also of some pentenes and hexenes. Michael and Brunei obtained tertiary butyl alcohol as well as the iodide in the reaction between isobutene and aqueous hydriodic acid.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/ja01317a056DOIArticle
http://resolver.caltech.edu/CaltechTHESIS:03232017-083732057Related ItemAlso published as part of author's PhD thesis
Alternate Title:Hydration Rate of Isobutene in Dilute Nitric Acid
Additional Information:Publication Date: Feb. 1934
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Gates Chemical Laboratory384
Issue or Number:2
Record Number:CaltechAUTHORS:20190211-144058865
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190211-144058865
Official Citation:J. Am. Chem. Soc. 1934, 56, 2, 460-464
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:92837
Collection:CaltechAUTHORS
Deposited By: Katherine Johnson
Deposited On:11 Feb 2019 22:45
Last Modified:03 Oct 2019 20:48

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