Fu, Gregory Chung-Wei (2019) Nucleophilic substitution reactions: A radical alternative to SN_1 and SN_2 reactions. In: 257th ACS National Meeting & Exposition, 31 March - 4 April 2019, Orlando, FL. https://resolver.caltech.edu/CaltechAUTHORS:20190318-073543823
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Abstract
Classical methods for achieving nucleophilic substitutions of alkyl electrophiles (SN_1 and SN_2) have limited scope and are not generally amenable to enantioselective variants that employ readily available racemic electrophiles. In this presentation, we will describe how the combination of radical chem. and transition-metal catalysis has opened the door to addressing the challenges of reactivity and of enantioselectivity in nucleophilic substitution reactions of secondary and tertiary alkyl electrophiles.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2019 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20190318-073543823 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20190318-073543823 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 93900 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 18 Mar 2019 15:55 | ||||||
| Last Modified: | 03 Oct 2019 20:58 |
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