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Luminescent tungsten arylisocyanide complexes

Winkler, Jay Richmond and Fajardo, Javier (2019) Luminescent tungsten arylisocyanide complexes. In: 257th ACS National Meeting & Exposition, 31 March - 4 April 2019, Orlando, FL. http://resolver.caltech.edu/CaltechAUTHORS:20190318-073956089

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Abstract

Homoleptic tungsten arylisocyanide complexes have remarkable spectroscopic and photophys. properties: metal-toligand charge-transfer absorption coeffs. on the order of 10^5 M^(-1) cm^(-1), luminescence quantum efficiencies as high as 25%, and excited-state lifetimes longer than 1 s. Moreover, the two-photon absorption cross sections of these complexes (1000-2000 10^(-50) cm^4 s photon^(-1) at 811 nm) are 10-100 times greater than those of many com. 2-photon dyes. We are working to understand these unique properties and to discover new mols. with enhanced characteristics. Our current efforts are aimed at prepg. fused-ring arylisocyanide ligands and developing protocols to use them in the synthesis of new homoleptic tungsten complexes.


Item Type:Conference or Workshop Item (Paper)
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https://www.acs.org/content/acs/en/meetings/national-meeting.htmlOrganizationConference Website
ORCID:
AuthorORCID
Winkler, Jay Richmond0000-0002-4453-9716
Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20190318-073956089
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20190318-073956089
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:93901
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:18 Mar 2019 15:54
Last Modified:18 Mar 2019 15:54

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