CaltechAUTHORS
  A Caltech Library Service

Electronic structures and electrochemistry of boronated cyanometalates

Gray, Harry B. and McNicholas, Brendon and Despagnet-Ayoub, Emmanuelle and Ngo, Danh (2019) Electronic structures and electrochemistry of boronated cyanometalates. In: 257th ACS National Meeting & Exposition, 31 March - 4 April 2019, Orlando, FL. https://resolver.caltech.edu/CaltechAUTHORS:20190325-095401293

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20190325-095401293

Abstract

We have synthesized and structurally characterized a series of organoboron-modified cyanometalates. The redn. potentials of these modified metal complexes span an exceptionally wide range, owing to variations in the electronic properties of the appended organoboron derivs. Selected highly sol. redox pairs exhibit electrochem. reversibility over a 2.1 V range in non-aq. solvents, making them excellent candidates for non-aq. redox flow batteries. Our model flow battery systems exhibit near unity Coulombic efficiencies and high energy efficiencies.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
https://www.acs.org/content/acs/en/meetings/national-meeting.htmlOrganizationConference Website
ORCID:
AuthorORCID
Gray, Harry B.0000-0002-7937-7876
McNicholas, Brendon0000-0002-3654-681X
Despagnet-Ayoub, Emmanuelle0000-0002-9013-7574
Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20190325-095401293
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190325-095401293
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:94108
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:25 Mar 2019 16:57
Last Modified:22 Nov 2019 09:58

Repository Staff Only: item control page