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Electronic structures and electrochemistry of boronated cyanometalates

Gray, Harry B. and McNicholas, Brendon and Despagnet-Ayoub, Emmanuelle and Ngo, Danh (2019) Electronic structures and electrochemistry of boronated cyanometalates. In: 257th ACS National Meeting & Exposition, 31 March - 4 April 2019, Orlando, FL.

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We have synthesized and structurally characterized a series of organoboron-modified cyanometalates. The redn. potentials of these modified metal complexes span an exceptionally wide range, owing to variations in the electronic properties of the appended organoboron derivs. Selected highly sol. redox pairs exhibit electrochem. reversibility over a 2.1 V range in non-aq. solvents, making them excellent candidates for non-aq. redox flow batteries. Our model flow battery systems exhibit near unity Coulombic efficiencies and high energy efficiencies.

Item Type:Conference or Workshop Item (Paper)
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URLURL TypeDescription Website
Gray, Harry B.0000-0002-7937-7876
McNicholas, Brendon0000-0002-3654-681X
Despagnet-Ayoub, Emmanuelle0000-0002-9013-7574
Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20190325-095401293
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:94108
Deposited By: Tony Diaz
Deposited On:25 Mar 2019 16:57
Last Modified:22 Nov 2019 09:58

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