Williams, Ellen D. and Thiel, Patricia A. and Weinberg, W. Henry and Yates, John T. (1979) Two‐Dimensional Phase Separation: Co-Adsorption of Hydrogen and Carbon Monoxide on the (111) Surface of Rhodium. In: The Physics of Surfaces: Aspects of the Kinetics and Dynamics of Surface Reaction. AIP Conference Proceedings. No.61. American Institute of Physics , New York, NY, pp. 275-283. ISBN 0-88318-160-6. http://resolver.caltech.edu/CaltechAUTHORS:20190402-142241299
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Abstract
The co‐adsorption of CO and H_2 on Rh(111) at low temperature (∼ 100 K) has been studied using thermal desorption mass spectrometry (TDS) and Low‐Energy Electron Diffraction(LEED). The probability of adsorption of CO on rhodium pretreated with hydrogen has been found to decrease slowly with increasing amounts of hydrogen on the surface. In addition, the effect of surface hydrogen on the CO LEED patterns indicates segregation of hydrogen and CO. These results can be explained in terms of a strong repulsive CO–H interaction and a mobile precursor model of CO adsorption.
| Item Type: | Book Section | ||||||||||
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| Additional Information: | © 1980 American Institute of Physics. Research supported by the National Science Foundation under Grant No. CHE77-16314. | ||||||||||
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| Record Number: | CaltechAUTHORS:20190402-142241299 | ||||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20190402-142241299 | ||||||||||
| Official Citation: | Two‐Dimensional Phase Separation: Co‐Adsorption of Hydrogen and Carbon Monoxide on the (111) Surface of Rhodium. Ellen D. Williams, Patricia A. Thiel, W. Henry Weinberg, and John T. Yates Jr. AIP Conference Proceedings 1980 61:1, 275-283; doi: 10.1063/1.2948590 | ||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||
| ID Code: | 94376 | ||||||||||
| Collection: | CaltechAUTHORS | ||||||||||
| Deposited By: | Tony Diaz | ||||||||||
| Deposited On: | 02 Apr 2019 21:41 | ||||||||||
| Last Modified: | 02 Apr 2019 21:41 |
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