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The Molecule-Electrode Interface in Single-Molecule Transistors

Yu, Hongbin and Luo, Yi and Beverly, Kristen and Stoddart, J. Fraser and Tseng, Hsian-Rong and Heath, James R. (2003) The Molecule-Electrode Interface in Single-Molecule Transistors. Angewandte Chemie International Edition, 42 (46). pp. 5706-5711. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20190516-093543949

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Abstract

What's in the middle matters little! Differential conductance measurements made on single‐molecule rotaxanes and their precursor dumbbells in transistors with platinum electrodes reflect the molecule–electrode contacts rather than the middle section of the molecules (see diagram; the color reflects the conductance, with dark corresponding to zero current). Interface states dominate electron transport. Molecular signatures are masked and even constitutional asymmetry in the molecule is difficult to detect.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1002/anie.200352352DOIArticle
ORCID:
AuthorORCID
Stoddart, J. Fraser0000-0003-3161-3697
Heath, James R.0000-0001-5356-4385
Additional Information:© 2003 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. Received: July 10, 2003. We thank Professor Hongkun Park and Wenjie Liang for helpful discussions, and the Department of Energy (DOE) and the Defense Advanced Research Projects Agency (DARPA), including the MARCO Center, for funding.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)UNSPECIFIED
Defense Advanced Research Projects Agency (DARPA)UNSPECIFIED
Microelectronics Advanced Research Corporation (MARCO)UNSPECIFIED
Subject Keywords:break junctions; differential conductance; molecular devices · molecule electrode contact; rotaxanes
Issue or Number:46
Record Number:CaltechAUTHORS:20190516-093543949
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190516-093543949
Official Citation:Yu, H. , Luo, Y. , Beverly, K. , Stoddart, J. F., Tseng, H. and Heath, J. R. (2003), The Molecule–Electrode Interface in Single‐Molecule Transistors. Angewandte Chemie International Edition, 42: 5706-5711. doi:10.1002/anie.200352352
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:95534
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:16 May 2019 22:13
Last Modified:03 Oct 2019 21:14

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