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Molecular-Mechanical Switch-Based Solid-State Electrochromic Devices

Steuerman, David W. and Tseng, Hsian-Rong and Peters, Andrea J. and Flood, Amar H. and Jeppesen, Jan O. and Nielsen, Kent A. and Stoddart, J. Fraser and Heath, James R. (2004) Molecular-Mechanical Switch-Based Solid-State Electrochromic Devices. Angewandte Chemie International Edition, 43 (47). pp. 6486-6491. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20190516-094412309

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Abstract

You only need eyes to appreciate the color change that occurs in a polymer matrix when the bistable rotaxane shown is switched between its ground‐state (green) and metastable‐state (red) co‐conformers. Not only is an electrochromic device within reach, but a universal switching mechanism seems to be on the cards.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1002/anie.200461723DOIArticle
ORCID:
AuthorORCID
Stoddart, J. Fraser0000-0003-3161-3697
Heath, James R.0000-0001-5356-4385
Additional Information:© 2004 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. Received: August 19, 2004. This research was funded by the Office of Naval Research, the National Science Foundation, and the Moletronics Program of the Defense Advanced Research Projects Agency, the Microelectronics Advanced Research Corporation, its Focus Centers on Functional Engineered NanoArchitectonics and Advanced Materials and Devices, and the Center for Nanoscale Innovation for Defense.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
NSFUNSPECIFIED
Defense Advanced Research Projects Agency (DARPA)UNSPECIFIED
Microelectronics Advanced Research Corporation (MARCO)UNSPECIFIED
Focus Center on Function Engineered NanoArchitectonics (FENA)UNSPECIFIED
Center for Nanoscale Innovation for Defense (CNID)UNSPECIFIED
Subject Keywords:catenanes; electrochromic devices; metastable compounds; polymers; rotaxanes
Issue or Number:47
Record Number:CaltechAUTHORS:20190516-094412309
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190516-094412309
Official Citation:Steuerman, D. W., Tseng, H. , Peters, A. J., Flood, A. H., Jeppesen, J. O., Nielsen, K. A., Stoddart, J. F. and Heath, J. R. (2004), Molecular‐Mechanical Switch‐Based Solid‐State Electrochromic Devices. Angewandte Chemie International Edition, 43: 6486-6491. doi:10.1002/anie.200461723
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:95535
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:16 May 2019 17:53
Last Modified:03 Oct 2019 21:14

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