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Starched Carbon Nanotubes

Star, Alexander and Steuerman, David W. and Heath, James R. and Stoddart, J. Fraser (2002) Starched Carbon Nanotubes. Angewandte Chemie International Edition, 41 (14). pp. 2508-2512. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20190516-095057730

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Abstract

Common‐or‐garden starch can render single‐walled carbon nanotubes (SWNTs) readily soluble in water. The secret is to preorganize the linear amylose component in the starch into a helix with iodine prior to bringing the SWNTs on the scene. The SWNTs displace the iodine molecules in a “pea‐shooting” type of mechanism (see scheme). After some physical cajoling of the aqueous solution containing the starch–SWNT complex, a fine “bucky paper” is formed. Spitting in the aqueous solution, followed by sitting around for a few hours, also enables equally fine “bucky paper” to be harvested.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1002/1521-3773(20020715)41:14<2508::aid-anie2508>3.0.co;2-aDOIArticle
ORCID:
AuthorORCID
Heath, James R.0000-0001-5356-4385
Stoddart, J. Fraser0000-0003-3161-3697
Additional Information:© 2002 Wiley‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany. Received: February 26, 2002. This work was funded by the Office of Naval Research and by the National Science Foundation.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
NSFUNSPECIFIED
Subject Keywords:amylose; hydrophobic interactions; molecular recognition; nanotubes; self‐assembly
Issue or Number:14
Record Number:CaltechAUTHORS:20190516-095057730
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190516-095057730
Official Citation:Star, A. , Steuerman, D. W., Heath, J. R. and Stoddart, J. F. (2002), Starched Carbon Nanotubes. Angewandte Chemie International Edition, 41: 2508-2512. doi:10.1002/1521-3773(20020715)41:14<2508::AID-ANIE2508>3.0.CO;2-A
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:95536
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:16 May 2019 18:04
Last Modified:03 Oct 2019 21:14

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