Star, Alexander and Steuerman, David W. and Heath, James R. and Stoddart, J. Fraser (2002) Starched Carbon Nanotubes. Angewandte Chemie International Edition, 41 (14). pp. 2508-2512. ISSN 1433-7851. doi:10.1002/1521-3773(20020715)41:14<2508::aid-anie2508>3.0.co;2-a. https://resolver.caltech.edu/CaltechAUTHORS:20190516-095057730
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Abstract
Common‐or‐garden starch can render single‐walled carbon nanotubes (SWNTs) readily soluble in water. The secret is to preorganize the linear amylose component in the starch into a helix with iodine prior to bringing the SWNTs on the scene. The SWNTs displace the iodine molecules in a “pea‐shooting” type of mechanism (see scheme). After some physical cajoling of the aqueous solution containing the starch–SWNT complex, a fine “bucky paper” is formed. Spitting in the aqueous solution, followed by sitting around for a few hours, also enables equally fine “bucky paper” to be harvested.
| Item Type: | Article | ||||||
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| Additional Information: | © 2002 Wiley‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany. Received: February 26, 2002. This work was funded by the Office of Naval Research and by the National Science Foundation. | ||||||
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| Subject Keywords: | amylose; hydrophobic interactions; molecular recognition; nanotubes; self‐assembly | ||||||
| Issue or Number: | 14 | ||||||
| DOI: | 10.1002/1521-3773(20020715)41:14<2508::aid-anie2508>3.0.co;2-a | ||||||
| Record Number: | CaltechAUTHORS:20190516-095057730 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20190516-095057730 | ||||||
| Official Citation: | Star, A. , Steuerman, D. W., Heath, J. R. and Stoddart, J. F. (2002), Starched Carbon Nanotubes. Angewandte Chemie International Edition, 41: 2508-2512. doi:10.1002/1521-3773(20020715)41:14<2508::AID-ANIE2508>3.0.CO;2-A | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 95536 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 16 May 2019 18:04 | ||||||
| Last Modified: | 16 Nov 2021 17:13 |
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