CaltechAUTHORS
  A Caltech Library Service

Synthesis and reactivity of group 4 complexes supported by redox noninnocent anthracene-bisphenoxide ligands

Bruening, Meaghan and Low, Choon Heng and Agapie, Theodor (2019) Synthesis and reactivity of group 4 complexes supported by redox noninnocent anthracene-bisphenoxide ligands. In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA. https://resolver.caltech.edu/CaltechAUTHORS:20190812-091932708

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20190812-091932708

Abstract

Transition metal complexes with pendant arenes have been demonstrated to support diverse chem. including deoxygenation of CO, carbide-CO coupling, nitride-CO coupling, CO_2 activation, and cross-coupling chem. To further expand on the utility of pendant arenes in redox chem., an anthracene linked bisphenoxide ligand was designed for early transition metals. Two electron chem. was obsd. with Zr and Ti complexes where the redox events are based on the anthracene motif. Transformations such as C-C reductive coupling and oxidative coupling of alkynes with nitriles or CO_2 have been obsd. Pyrimidines can be prepd. catalytically with high selectivity in this system. The role of the redox-active anthracene motif will be discussed.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
https://www.acs.org/content/acs/en/meetings/national-meeting.htmlOrganizationConference Website
ORCID:
AuthorORCID
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20190812-091932708
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190812-091932708
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:97753
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:12 Aug 2019 17:27
Last Modified:03 Oct 2019 21:34

Repository Staff Only: item control page