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Fundamental lessons in carbon fixation chemistry: Molybdenum-mediated reduction of C_1 oxygenates

Buss, Joshua Alan and Agapie, Theodor (2019) Fundamental lessons in carbon fixation chemistry: Molybdenum-mediated reduction of C_1 oxygenates. In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA. https://resolver.caltech.edu/CaltechAUTHORS:20190812-092302497

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Abstract

The controlled redn. of CO_2 and CO to C≥2 products is crit. for the synthesis of clean fuels, but these multi-electron reactions are challenging to control and mechanistically poorly understood. A series of Mo complexes, bearing a terphenyl diphosphine ligand scaffold, shed light on important mechanistic aspects of CO_2 redn., CO deoxygenation, and CO reductive catenation. A rare example of a terminal Mo carbide complex acts as a precursor to downstream C-C coupling chemistries. Low temp. synthesis and spectroscopy, kinetics, and isotopic labeling provide key insights into design elements that promote advantageous reactivity, while mapping out the elementary steps by which C_1 oxygenates are reduced and coupled at a single metal site.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
https://www.acs.org/content/acs/en/meetings/national-meeting.htmlOrganizationConference Website
ORCID:
AuthorORCID
Buss, Joshua Alan0000-0002-3347-8583
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20190812-092302497
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190812-092302497
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:97754
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:12 Aug 2019 17:12
Last Modified:03 Oct 2019 21:34

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