Xiong, Shuoyan and Agapie, Theodor (2019) Nickel-based bimetallic catalysts for Olefin polymerization. In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA. https://resolver.caltech.edu/CaltechAUTHORS:20190812-131301286
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Abstract
The insertion polymn. of polar monomers remains a significant challenge in polyolefin synthesis. Multimetallic catalysts may be suitable candidates to address this problem via secondary metal centers' electronic, steric or metal-metal cooperative effects. We have prepd. binucleating phenoxide ligands and utilized them to support mono-nickel complexes. Treatment with second metal precursors results in the formation of heterobimetallic complexes. The effect of the bimetallic catalyst structure on olefin polymn. behavior will be discussed.
Item Type: | Conference or Workshop Item (Paper) | ||||||
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Additional Information: | © 2019 American Chemical Society. | ||||||
Record Number: | CaltechAUTHORS:20190812-131301286 | ||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20190812-131301286 | ||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
ID Code: | 97778 | ||||||
Collection: | CaltechAUTHORS | ||||||
Deposited By: | Tony Diaz | ||||||
Deposited On: | 12 Aug 2019 20:50 | ||||||
Last Modified: | 03 Oct 2019 21:34 |
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