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Nickel-based bimetallic catalysts for Olefin polymerization

Xiong, Shuoyan and Agapie, Theodor (2019) Nickel-based bimetallic catalysts for Olefin polymerization. In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA.

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The insertion polymn. of polar monomers remains a significant challenge in polyolefin synthesis. Multimetallic catalysts may be suitable candidates to address this problem via secondary metal centers' electronic, steric or metal-metal cooperative effects. We have prepd. binucleating phenoxide ligands and utilized them to support mono-nickel complexes. Treatment with second metal precursors results in the formation of heterobimetallic complexes. The effect of the bimetallic catalyst structure on olefin polymn. behavior will be discussed.

Item Type:Conference or Workshop Item (Paper)
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Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20190812-131301286
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:97778
Deposited By: Tony Diaz
Deposited On:12 Aug 2019 20:50
Last Modified:03 Oct 2019 21:34

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