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Homogeneous Catalysis: Organometallic Catalysis and Organocatalysis

Grubbs, Robert H. (2018) Homogeneous Catalysis: Organometallic Catalysis and Organocatalysis. In: Catalysis in Chemistry and Biology. World Scientific , Hackensack, NJ, pp. 3-8. ISBN 9789813237162. https://resolver.caltech.edu/CaltechAUTHORS:20190812-142546569

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Abstract

Although soluble catalysts have been used in organic chemistry for many years, until the 1960s they involved simple acids, bases, or metal salts. In most cases, the metals were ignored in any mechanistic considerations. For example, copper salts can catalyze the cyclopropanation of olefins using diazo compounds; however, the role of copper was not considered in early mechanisms. Simple soluble nickel and cobalt precursor complexes were used in some industrial processes but were not extensively studied. Heterogeneous catalysis especially for hydrogenation has a much longer history of use in organic synthesis…


Item Type:Book Section
Related URLs:
URLURL TypeDescription
https://doi.org/10.1142/9789813237179_0001DOIArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2018 World Scientific Publishing Co Pte Ltd.
Record Number:CaltechAUTHORS:20190812-142546569
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190812-142546569
Official Citation:HOMOGENEOUS CATALYSIS: ORGANOMETALLIC CATALYSIS AND ORGANOCATALYSIS. ROBERT H. GRUBBS. Catalysis in Chemistry and Biology. August 2018, 3-8. doi: 10.1142/9789813237179_0001
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:97793
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:09 Mar 2020 14:56
Last Modified:03 Oct 2019 21:35

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