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Newest advances in enzymatic carbene- and nitrene-transfer catalysis

Arnold, Frances Hamilton (2019) Newest advances in enzymatic carbene- and nitrene-transfer catalysis. In: 257th ACS National Meeting & Exposition, 31 March-4 April 2019, Orlando, FL. https://resolver.caltech.edu/CaltechAUTHORS:20190823-075522116

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Abstract

By combining advances in chemocatalysis with directed evolution we can further expand Nature's vast catalyst repertoire. I will describe recently developed carbene- and nitrene-transfer reactions, first envisioned and invented by human chemists, that are now genetically encoded and catalyzed by heme proteins and can be tuned by directed evolution. I argue that we should look at the biol. world not just for the chem. that it already does so well, but for chem. it could do in the future, with some human creativity and a little help from evolution.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
https://global.acs.org/events/257th-acs-national-meeting-expositionOrganizationConference Website
ORCID:
AuthorORCID
Arnold, Frances Hamilton0000-0002-4027-364X
Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20190823-075522116
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20190823-075522116
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:98139
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:23 Aug 2019 15:40
Last Modified:03 Oct 2019 21:38

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