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Transition‐Metal‐Free Catalytic C─H Bond Silylation

Schuman, David P. and Liu, Wen‐Bo and Nesnas, Nasri and Stoltz, Brian M. (2019) Transition‐Metal‐Free Catalytic C─H Bond Silylation. In: Organosilicon Chemistry: Novel Approaches and Reactions. Wiley , pp. 213-240. ISBN 9783527344536.

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Herein, we provide a detailed look at the state of transition‐metal‐free catalytic C–H silylation with select examples to highlight specific advances during the field's recent development. The reactions are categorized by type of catalyst (i.e. Lewis acid, Brønsted acid, Brønsted base, and radical initiation catalysts). For each catalyst system presented, an overview of the substrate scope, mechanism (if known), and significant limitations is discussed.

Item Type:Book Section
Related URLs:
URLURL TypeDescription
Nesnas, Nasri0000-0003-3511-940X
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2020 Wiley‐VCH Verlag GmbH & Co. KGaA. Published Online: 08 November 2019; Published Print: 11 November 2019.
Subject Keywords:transition‐metal‐free; catalysis; green chemistry; dehydrogenation; silylation
Record Number:CaltechAUTHORS:20191111-083817296
Persistent URL:
Official Citation:Schuman, D.P., Liu, W.‐B., Nesnas, N. and Stoltz, B.M. (2019). Transition‐Metal‐Free Catalytic C─H Bond Silylation. In Organosilicon Chemistry (eds T. Hiyama and M. Oestreich).
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:99769
Deposited By: Tony Diaz
Deposited On:12 Nov 2019 22:36
Last Modified:16 Nov 2021 17:49

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