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Article
Symmetry, Transactions, and the Mechanism of Wave
Function Collapse
John G. Cramer
1
and Carver A. Mead
2
1
Department of Physics, University of Washington, Seattle, WA 98195; jcramer@uw.edu
2
California Institute of Technology, Pasadena, CA 91125; carver@caltech.edu
*
Correspondence: jcramer@uw.edu
Received: date; Accepted: date; Published: date
Abstract:
The Transactional Interpretation of quantum mechanics exploits the intrinsic time-symmetry
of wave mechanics to interpret the
ψ
and
ψ
* wave functions present in all wave mechanics calculations
as representing retarded and advanced waves moving in opposite time directions that form a quantum
"handshake" or transaction. This handshake is a standing-wave that builds up across space-time to
transfer the conserved quantities of energy, momentum, and angular momentum in an interaction. Here
we derive a two-atom quantum formalism describing a transaction. Using this, we perform calculations
employing the standard wave mechanics of Schrödinger to show the transfer of energy from a hydrogen
atom in an excited state to a nearby hydrogen atom in its ground state, using the retarded and advanced
electromagnetic four-potentials. It is seen that the initial exchange creates a dynamically unstable situation
that avalanches to the completed transaction, demonstrating that wave function collapse, considered
mysterious in the literature, can be implemented in the Schrödinger formalism by including advanced
potentials without the introduction of any additional mechanism or formalism.
Keywords:
quantum mechanics; transaction; transactional interpretation; wave function collapse;
collapse mechanism
1. Introduction
Quantum mechanics (QM) was never properly finished. Instead, it was left in an exceedingly
unsatisfactory state by its founders. Many attempts by highly qualified individuals to improve the
situation have failed to produce any consensus about either (a) the precise nature of the problem, or (b)
what a better form of QM might look like.
At the most basic level, a simple observation illustrates the central conceptual problem:
An excited atom somewhere in the universe transfers
all
of its excitation energy to another single atom,
independent of the presence of the vast number of alternative atoms that could have received all or part of
the energy. The obvious "photon-as-particle" interpretation of this situation has a one-way symmetry: The
excited source atom is depicted as emitting a particle, a
photon
of electromagnetic energy that is somehow
oscillating with angular frequency
ω
while moving in a particular direction. The photon is depicted as
carrying a quantum of energy
̄
h
ω
, a momentum
̄
h
ω
/
c
, and an angular momentum
̄
h
through space, until it
is later absorbed by some unexcited atom. The emission and absorption are treated as independent unitary
events without internal structure. It is insisted that the only real and meaningful quantities describing this
process are
probabilities
, since these are measurable. The necessarily abrupt change in the quantum wave
function of the system when the photon arrives (and an observer potentially gains information) is called
"wave function collapse" and is considered to be a mysterious process that the founders of QM found it
necessary to "put in by hand" without providing any mechanism.
Further, there is the unresolved problem of
entanglement
. Over the past few decades, many increasingly
exquisite "EPR" experiments have demonstrated that multi-body quantum systems with separated
arXiv:2006.11365v1 [quant-ph] 19 Jun 2020
2 of 34
components that are subject to conservation laws exhibit a property called "quantum entanglement"[
1
]:
Their component wave functions are inextricably locked together, and they display a nonlocal correlated
behavior enforced over an arbitrary interval of space-time without any hint of an underlying mechanism
or any show of respect for our cherished classical "arrow of time." Entanglement is the most mysterious of
the many so-called "quantum mysteries."
It has thus become clear that the quantum transfer of energy must have quite a different symmetry
from that implied by this simple "photon-as-particle" interpretation. Within the framework of statistical
QM, the intrinsic symmetry of the energy transfer and the mechanisms behind wave function collapse
and entanglement have been greatly clarified by the
Transactional Interpretation of quantum mechanics
(TI), developed over several decades by one of us
1
and recently described in some detail in the book
The
Quantum Handshake
[1], of which this paper is, in part, a review.
1.1. Wheeler-Feynman Electrodynamics
The Transactional Interpretation was inspired by classical time-symmetric Wheeler-Feynman
electrodynamics[
5
,
6
] (WFE), sometimes called "absorber theory".
Basically, WFE assumes that
electrodynamics must be time-symmetric, with equally valid retarded waves (that arrive
after
they are
emitted) and advanced waves (that arrive
before
they are emitted). WFE describes a "handshake" process
accounting for emission recoil in which the emission of a retarded wave stimulates a future absorber to
produce an advanced wave that arrives back at the emitter at the instant of emission. WFE is based on
electrodynamic time symmetry but has been shown to be completely interchangeable with conventional
classical electrodynamics in its predictions.
WFE asserts that the breaking of the intrinsic time-symmetry to produce the electromagnetic arrow of
time, i.e., the observed dominance of retarded radiation and absence of advanced radiation in the universe,
arises from the presence of more absorption in the future than in the past. In an expanding universe, that
assertion is questionable. One of us has suggested an alternative cosmological explanation[
7
], which
employs advanced-wave termination and reflection from the singularity of the Big Bang.
1.2. The Transactional Interpretation of Quantum Mechanics
The Transactional Interpretation of quantum mechanics[
1
] takes the concept of a WFE handshake
from the classical regime into the quantum realm of photons and massive particles. The retarded and
advanced waves of WFE become the quantum wave functions
ψ
and
ψ
*. Note that the complex conjugation
of
ψ
* is in effect the application of the Wigner time-reversal operator, thus representing an advanced wave
function that carries negative energy from the present to the past.
Some critics of the Transactional Interpretation have questioned why it does not provide a detailed
mathematical description of how a transaction forms
2
. This question, of course, betrays a fundamental
misunderstanding of what an
interpretation
of quantum mechanics actually is. In our view, the mathematics
is (and should be) exclusively contained in the quantum mechanics formalism itself. The function of the
interpretation is to
interpret
that mathematics, not to introduce some additional variant formalism.
3
In the
1
We note that Ruth Kastner has extended her "probabilist" variant of the TI into the quantum-relativistic domain[
2
,
3
] and has
used it to extend and enhance the "decoherence" approach to quantum interpretation[4].
2
Here we have done just that, except not as an interpretation but as a calculation using the Schrödinger formalism.
3
We note, however, that this principle is violated by the Bohm-de Broglie "interpretation", by the Ghirardi-Rimini-Weber
"interpretation", and by many other so-called interpretations that take the questionable liberty of modifying the standard QM
formalism. In that sense, these are alternative variant quantum theories,
not
interpretations at all.
3 of 34
present work, we use the standard Schrödinger wave mechanics formalism
with the inclusion of retarded and
advanced electromagnetic four-potentials
to describe and illuminate the processes of transaction formation
and the collapse of the wave function.
The TI leans heavily on the standard formalism of Schrödinger wave mechanics. However, that
formalism is conventionally regarded as not containing any mathematics that explicitly accounts for wave
function collapse (which the TI interprets as
transaction formation
). Here we show that this is incorrect, and
that the Schrödinger formalism with the inclusion of retarded and advanced 4-potentials can provide a
detailed mathematical description of a "quantum-jump" in which what seems to be a photon is emitted
by one hydrogen atom in an excited state and excites another hydrogen atom initially in its ground state.
Thus, the mysterious process of wave function collapse becomes just a phenomenon involving an exchange
of waves that is actually a part of the Schrödinger formalism.
As illustrated in Fig. 1, the process described involves the initial existence in each atom of a very
small admixture of the wave function for the opposite state, thereby forming two-component states in
both atoms. This causes them to become weak dipole radiators oscillating at the same difference frequency
ω
. The interaction that follows, characterized by a retarded-advanced exchange of 4-vector potentials,
leads to an exponential build-up of a transaction, resulting in the complete transfer of one photon-worth
of energy ̄
h
ω
from one atom to the other. This process is described in more detail below.
Figure 1.
Model of transaction formation: An emitter atom
2 in a space-antisymmertric excited state
of energy
E
2
and an absorber atom
1 in a space-symmetric ground state of energy
E
1
both have slight
admixtures of the other state, giving both atoms dipole moments that oscillate with the same difference
frequency
ω
=
ω
2
ω
1
. If the relative phase of the initial small offer
ψ
and confirmation
ψ
waves is
optimal, this condition initiates energy transfer, which avalanches to complete transfer of one photon-worth
of energy ̄
h
ω
.
2. Physical Mechanism of the Transfer
The standard formalism of QM consists of a set of arbitrary rules, conventionally viewed as dealing
only with probabilities. When illuminated by the TI, that formalism hints at an underlying physical
mechanism that might be understood, in the usual sense of the concept
understood
. The first glimpse of
such an understanding, and of the physical nature of the transactional symmetry, was suggested by Gilbert
N. Lewis in 1926[8], the same year he gave the energy transfer the name "photon":
4 of 34
It is generally assumed that a radiating body emits light in every direction, quite regardless of whether
there are near or distant objects which may ultimately absorb that light; in other words that it radiates
"into space"...
I am going to make the contrary assumption that an atom never emits light except to another atom...
I propose to eliminate the idea of mere emission of light and substitute the idea of transmission, or a process
of exchange of energy between two definite atoms... Both atoms must play coordinate and symmetrical
parts in the process of exchange...
In a pure geometry it would surprise us to find that a true theorem becomes false when the page upon
which the figure is drawn is turned upside down. A dissymmetry alien to the pure geometry of relativity
has been introduced by our notion of causality.
In what follows we demonstrate that the pair of coupled Schrödinger equations describing the two
atoms, as coupled by a relativistically correct description of the electromagnetic field, exhibit a unique
solution. This solution has exactly the symmetry of the TI and thus provides a
physically understandable
mechanism for the experimentally observed behavior: Both atoms, in the words of Lewis, "
play coordinate
and symmetrical parts in the process of exchange.
"
The solution gives a smooth transition in each of the atomic wave functions, brought to abrupt closure
by the highly nonlinear increase in coupling as the transition proceeds. The origin of statistical behavior
and "quantum randomness" can be understood in terms of the random distribution of wave-function
amplitudes and phases provided by the perturbations of the many other potential recipient atoms; no
"hidden variables" are required. These findings might be viewed as a first step towards a physical
understanding of the process of quantum energy transfer.
We will close by indicating the deep, fundamental questions that we have not addressed, and that
must be understood before anything like a complete physical understanding of QM is in hand.
3. Quantum States
In 1926, Schrödinger, seeking a wave-equation description of a quantum system with mass, adopted
Planck’s notion that energy was somehow proportional to frequency together with deBroglie’s idea that
momentum was the propagation vector of a wave and crafted his wave equation for the time evolution of
the wave function
Ψ
[9]:
̄
h
2
m i
2
Ψ
+
q
e
V
i
̄
h
Ψ
=
Ψ
t
.
(1)
Here
V
is the electrical potential and
q
e
is the (negative) charge on the electron. So what is the meaning of
the wave function
Ψ
that is being characterized? In modern treatments
Ψ
is called a "probability amplitude",
which has only a probabilistic interpretation. In what follows, however, we return to Schrödinger ’s original
vision, which provides a detailed physical picture of the wave function and how it interacts with other
charges:
The hypothesis that we have to admit is very simple, namely that the square of the absolute value of
Ψ
is proportional to an electric density, which causes emission of light according to the laws of ordinary
electrodynamics.
So we can visualize the electron as having a smooth charge distribution in 3-dimensional space,
whose density is given by
Ψ
Ψ
. There is no need for statistics at any point of the calculation, and none of
the quantities have statistical meaning. The probabilistic outcome of quantum experiments has the same
origin as it does in all other experiments—random perturbations beyond the control of the experimenter.
We return to the topic of probability after we have established the nature of the transaction.
5 of 34
For a local region of positive potential
V
, for example near a positive proton, the negative electron’s
wave function has a local potential energy (
q
e
V
) minimum in which the electron’s wave function can form
local
bound states
. The spatial shape of the wave function amplitude is a tradeoff between getting close to
the proton, which lowers its potential energy, and bunching together too much, which increases its
2
"kinetic energy." Eq. 1 is simply a mathematical expression of this tradeoff. A discrete set of states called
eigenstates
are standing-wave solutions of Eq. 1 of the form
Ψ
=
Re
i
ω
t
, where
R
and
V
are functions of
only the spatial coordinates, and the angular frequency
ω
is itself not a function of time. For the hydrogen
atom, the potential
V
=
e
0
q
p
/
r
, where
q
p
is the positive charge on the nucleus. Two of the lowest-energy
solutions to Eq. 1 with this potential are:
Ψ
100
=
e
r
π
e
i
ω
1
t
Ψ
210
=
r e
r
/2
cos
(
θ
)
4
6
π
e
i
ω
2
t
,
(2)
where the dimensionless radial coordinate
r
is the radial distance divided by the
Bohr radius
a
0
:
a
0
=
4
πe
0
̄
h
2
mq
2
=
0.0529 nm,
(3)
and
θ
is the azimuthal angle from the North Pole (
+
z
axis) of the spherical coordinate system.
The spatial "shape" of the two lowest energy eigenstates for the hydrogen atom is shown in Fig. 2. Here we
focus on the excited-state wave function
Ψ
210
that has no angular momentum projection on the z-axis. For
the moment, we set aside the wave functions
Ψ
21
±
1
, which have
+
1 and
1 angular momentum z-axis
projections. Because, for any single eigenstate, the electron density is
Ψ
Ψ
=
Re
i
ω
t
Re
i
ω
t
=
R
2
, the charge
density is not a function of time, so none of the other properties of the wave function change with time.
The individual eigenstates are thus
stationary states
. The lowest energy bound eigenstate for a given form
of potential minimum is called its
ground state
, shown on the left in Fig. 3. The corresponding charge
densities are shown in Fig. 4.
Already in 1926 Schrödinger had derived the energies and wave functions for the stationary solutions
of his equation for the hydrogen atom.
His physical insight, that the absolute square
Ψ
Ψ
of the wave function was the
electron density
, had
enabled him to work out the energy shifts of these levels caused by external applied electric and magnetic
fields, the expected strengths of the transitions between pairs of energy levels, and the polarization of light
from certain transitions. These predictions could be compared directly with experimental data, which had
been previously observed but not understood.
He reported that these calculations were:
...not at all difficult, but very tedious. In spite of their tediousness, it is rather fascinating to see all the
well-known but not understood "rules" come out one after the other as the result of familiar elementary
and absolutely cogent analysis, like e.g. the fact that
2
π
0
cos
m
φ
cos
n
φ
d
φ
vanishes unless
n
=
m
.
Once the hypothesis about
Ψ
Ψ
has been made, no accessory hypothesis is needed or is possible; none
could help us if the "rules" did not come out correctly. But fortunately they do[9,10].
Schrödinger’s approach allows us to describe continuous quantum transitions in a simple and
intuitively appealing way by extending the notions of Collective Electrodynamics[
11
] to the wave function
of a single electron. We shall require only the most rudimentary techniques of Schrödinger’s original
quantum theory.
6 of 34
Figure 2.
Angular dependence of the spatial wave function amplitudes for the lowest (100, left) and
next higher (210, right) states of the hydrogen atom, plotted as unit radius in spherical coordinates from
Eq. 2. The 100 wave function has spherical symmetry: Positive in all directions. The 210 wave function is
antisymmetric along the
z
axis, as indicated by the color change. In practice the direction of the
z
axis will
be established by an external electromagnetic field, as we shall analyze shortly.
-
10
-
5
0
5
10
0.0
0.1
0.2
0.3
0.4
0.5
z
-
10
-
5
0
5
10
-
0.05
0.00
0.05
z
Figure 3.
Wave function amplitudes for the 100 and 210 states, along the
z
axis of the hydrogen atom. The
horizontal axis in all plots is the position along the
z
axis in units of the Bohr radius.
4. The Two-State System
Let us first consider a simple two-state system. The system has a single positive charge distribution
around which there are two eigenstates, labeled 1 and 2, that an electron can occupy. In State 1, the electron
has wave function
Ψ
1
and energy
E
1
; in State 2, it has wave function
Ψ
2
and energy
E
2
>
E
1
:
Ψ
1
=
R
1
e
i
ω
1
t
Ψ
2
=
R
2
e
i
ω
2
t
,
(4)
where
ω
1
=
E
1
/ ̄
h
and
ω
2
=
E
2
/ ̄
h
.
We visualize the wave function as a representation of a totally continuous matter wave, and take
R
1
and
R
2
as real functions of the space coordinates. We can interpret all of the usual operations involving the
7 of 34
-
10
-
5
0
5
10
0.00
0.05
0.10
0.15
0.20
0.25
z
-
10
-
5
0
5
10
0.00
0.01
0.02
0.03
0.04
0.05
0.06
z
Figure 4.
Contribution of
x
y
"slices" at position
z
of wave function density
Ψ
Ψ
to the total charge or
mass of the 100 and 210 states of the hydrogen atom. Both curves integrate to 1.
wave function as methods for computing properties of this continuous distribution. The only particularly
quantal assumption involved is that the wave function obeys a
normalization condition
:
Ψ
Ψ
d
vol
=
1,
(5)
where the integral is taken over the entire three-dimensional volume where
Ψ
is non-vanishing
4
.
This condition assures that the total charge will be a single electronic charge, and the total mass will
be a single electronic mass.
By construction, the eigenstates of the Schrödinger equation are real and orthogonal:
R
1
R
2
d
vol
=
0.
(6)
The first moment
z
of the electron distribution
5
along the atom’s
z
axis is:
z
=
Ψ
z
Ψ
d
vol,
(7)
where the integral is taken over all space where the wave function is non-vanishing.
4
Envelope functions like
R
1
and
R
2
generally die out exponentially with distance sufficiently far from the "region of interest,"
such as an atom. Integrals like this one and those that follow are taken out far enough that the part being neglected is within the
tolerance of the calculation.
5
In statistical treatments
z
would be called the "expectation value of
z
", whereas for our continuous distribution it is called
the "average value of
z
" or the "first moment of z." The electron wave function is a
wave packet
and is subject to all the Fourier
properties of one, as treated at some length in ref.[
1
]. For example a packet only 100 wavelengths in duration has a spread in
frequency (and therefore energy) of order 1%, resulting, for example, in the observed
natural line width
of radiation from an
atom. Similarly, a packet confined within 100 wavelengths in dimension has a spread in wave vector (and therefore momentum)
of order 1%. Because statistical QM insisted that electrons were "point particles", one was no longer able to visualize how
they could exhibit interference or other wave properties, so a set of rules was constructed to make the outcomes of statistical
experiments come out right. Among these was the
uncertainty principle
, which simply restated the Fourier properties of an
object described by waves in a statistical context. No statistical attributes are attached to any properties of the wave function in
this treatment.
8 of 34
This moment gives the position of the center of negative charge of the electron wave function relative
to the positive charge on the nucleus. When multiplied by the electronic charge
q
, it is called
the electric
dipole moment q
z
of the charge distribution of the atom:
q
z
=
q
Ψ
z
Ψ
d
vol.
(8)
From Eq. 7 and Eq. 4, the dipole moment for the
i
th eigenstate is:
q
z
i
=
q
Ψ
i
z
Ψ
i
d
vol
=
q
R
i
z R
i
d
vol
=
q
R
2
i
z d
vol.
(9)
Pure eigenstates of the system will have a definite parity, i.e., they will have wave functions with
either even symmetry [
Ψ
(
z
) =
Ψ
(
z
)
], or odd symmetry [
Ψ
(
z
) =
Ψ
(
z
)
]. For either symmetry the
integral over
R
2
z
vanishes, and the dipole moment is zero. We note that even if the wave function did not
have even or odd symmetry, the dipole moment, and all higher moments as well, would be independent of
time. By their very nature, eigenstates are stationary states and can be visualized as standing-waves—none
of their physical spatial attributes can be functions of time.
The notion of stationarity is the quantum answer to the original question about atoms with electrons
orbiting a central nucleus:
Why doesn’t the electron orbiting the nucleus radiate its energy away?
In his 1917 book,
The Electron
, R.A. Millikan
6
anticipates the solution in his comment about the
. . . apparent contradiction involved in the non-radiating electronic orbit—a contradiction which would
disappear, however, if the negative electron itself, when inside the atom, were a ring of some sort, capable
of expanding to various radii, and capable, only when freed from the atom, of assuming essentially the
properties of a point charge.
Ten years before the statistical quantum theory was put in place, Millikan had clearly seen that a continuous,
symmetric electronic charge distribution would not radiate, and that the real problem was the assumption
of a point charge. The continuous wave nature of the electron implies a continuous charge distribution.
That smooth charge distribution can propagate around the nucleus and thereby generate a magnetic
moment, as observed in many atoms. The smooth propagation around the nucleus does not imply
radiation.
5. Transitions
In order to radiate electromagnetic energy, the charge distribution
must change with time
. Because the
spatial attributes of a system in a pure eigenstate are stationary, the system in such an eigenstate cannot
radiate energy. Because the eigenstates of the system form a complete basis set, any behavior of the system
can be expressed by forming a linear combination (superposition) of eigenstates. The general form of such
a superposition of two eigenstates is:
Ψ
=
ae
i
φ
a
R
1
e
i
ω
1
t
+
be
i
φ
b
R
2
e
i
ω
2
t
,
(10)
6
See [
12
]. Millikan was the first researcher to directly observe and measure the quantized charge on the electron with his famous
oil-drop experiment, for which he later received the Nobel prize. This reference contains a fascinating discussion of these
experiments, and a wonderful section contrasting the corpuscular and the ether theories of radiation.
9 of 34
where
a
and
b
are real amplitudes, and
φ
a
and
φ
b
are real constants that determine the phases of the
oscillations
ω
1
and
ω
2
.
Using
ω
0
=
ω
2
ω
1
and
φ
=
φ
a
φ
b
, the charge density
ρ
of the two-component-state wave function
is:
ρ
=
q
Ψ
Ψ
ρ
q
=
(
ae
i
φ
a
R
1
e
i
ω
1
t
+
be
i
φ
b
R
2
e
i
ω
2
t
)(
ae
i
φ
a
R
1
e
i
ω
1
t
+
be
i
φ
b
R
2
e
i
ω
2
t
)
=
a
2
R
2
1
+
b
2
R
2
2
+
(
ae
i
φ
a
be
i
φ
b
e
i
ω
0
t
+
be
i
φ
b
ae
i
φ
a
e
i
ω
0
t
)
R
1
R
2
=
a
2
R
2
1
+
b
2
R
2
2
+
ab
(
e
i
(
φ
b
φ
a
)
e
i
ω
0
t
+
e
i
(
φ
a
φ
b
)
e
i
ω
0
t
)
R
1
R
2
=
a
2
R
2
1
+
b
2
R
2
2
+
ab
(
e
i
ω
0
t
φ
+
e
i
ω
0
t
+
φ
)
R
1
R
2
=
a
2
R
2
1
+
b
2
R
2
2
+
2
abR
1
R
2
cos
(
ω
0
t
+
φ
)
.
(11)
So the charge density of the two-component wave function is made up of the charge densities of the two
separate wave functions, shown in Fig. 4, plus a term proportional to the product of the two wave function
amplitudes. It reduces to the individual charge density of the ground state when
a
=
1,
b
=
0 and to that of
the excited state when
a
=
0,
b
=
1. The product term, shown in green in Fig. 5, is the only non-stationary
term; it oscillates at the transition frequency
ω
0
. The integral of the total density shown in the right-hand
plot is equal to 1 for any phase of the cosine term, since there is only one electron in this two-component
state.
-
6
-
4
-
2
0
2
4
6
-
0.10
-
0.05
0.00
0.05
0.10
0.15
0.20
0.25
z
-
6
-
4
-
2
0
2
4
6
-
0.10
-
0.05
0.00
0.05
0.10
0.15
0.20
0.25
z
Figure 5.
Left:
Plot of the three terms in the wave-function density in Eq. 11 for an equal
(
a
=
b
=
1/
2
)
superposition of the ground state (
R
1
, blue) and first excited state (
R
2
, red) of the hydrogen atom. The green
curve is a snapshot of the time-dependent
R
1
R
2
product term, which oscillates at difference frequency
ω
0
.
Right:
Snapshot of the total charge density, which is the sum of the three curves in the left plot. The
magnitudes plotted are the contribution to the total charge in an
x
y
"slice" of
Ψ
Ψ
at the particular
z
coordinate. All plots are shown for the phase such that
cos
(
ω
0
t
+
φ
) =
1. The horizontal axis in each
plot is the spatial coordinate along the
z
axis of the atom, given in units of the Bohr radius
a
0
. Animation
here[32]
All the
Ψ
Ψ
plots represent the density of negative charge of the electron. The atom as a whole is
neutral because of the equal positive charge on the nucleus. The dipole is formed when the center of
10 of 34
charge of the electron wave function is displaced from the nucleus.
The two-component wave function must be normalized, since it is the state of one electron:
Ψ
Ψ
d
vol
=
1
=
(
ae
i
φ
a
R
1
e
i
ω
1
t
+
be
i
φ
b
R
2
e
i
ω
2
t
)
(
ae
i
φ
a
R
1
e
i
ω
1
t
+
be
i
φ
b
R
2
e
i
ω
2
t
)
d
vol
=
a
2
R
2
1
d
vol
+
b
2
R
2
2
d
vol
+
(
ae
i
φ
a
be
i
φ
b
e
i
ω
0
t
+
be
i
φ
b
ae
i
φ
a
e
i
ω
0
t
)
R
1
R
2
d
vol
.
(12)
Recognizing from Eq. 5 and Eq. 6 that the individual eigenfunctions are normalized and orthogonal:
R
2
1
d
vol
=
1
R
2
2
d
vol
=
1
R
1
R
2
d
vol
=
0.
(13)
Eq. 12 becomes
Ψ
Ψ
d
vol
=
1
=
a
2
+
b
2
.
(14)
So
a
2
represents the fraction of the two-component wave function made up of the lower state
Ψ
1
, and
b
2
represents the fraction made up of the upper state
Ψ
2
. The total energy
E
of a system whose wave function
is a superposition of two eigenstates is:
E
=
a
2
E
1
+
b
2
E
2
.
(15)
Using the normalization condition
a
2
+
b
2
=
1 and solving Eq. 15 for
b
2
, we obtain:
b
2
=
E
E
1
E
2
E
1
.
(16)
In other words,
b
2
is just the energy of the wave function, normalized to the transition energy, and using
E
1
as its reference energy. Taking
E
1
as our zero of energy and
E
0
=
E
2
E
1
, Eq. 16 becomes:
E
=
E
0
b
2
E
t
=
E
0
(
b
2
)
t
.
(17)
Using:
d
12
=
2
q
R
1
R
2
z
=
2
q
z
max
,
(18)
the dipole moment of such a superposition can, from Eq. 11, be written:
dipole moment
=
q
z
=
d
12
ab
cos
(
ω
0
t
+
φ
)
.
(19)
The factor
d
12
is called the
dipole matrix element
for the transition; it is a measure of the maximum
strength of the oscillating dipole moment. If one
R
is an even function of
z
and the other is an odd function
of
z
, as in the case of the 100 and 210 states of the hydrogen atom, then this factor is nonzero, and the
transition is said to be
electric dipole allowed
. If both
R
1
and
R
2
are either even or odd functions of
z
,
then this factor is zero, and the transition is said to be
electric dipole forbidden
. Even in this case, some
other moment of the distribution generally will be nonzero, and the transition can proceed by magnetic
11 of 34
dipole, magnetic quadrupole, or other higher-order moments. For now, we will concentrate on transitions
that are electric dipole allowed.
We have the time dependence of the electron dipole moment
q
z
from Eq. 19, from which we can
derive the velocity and acceleration of the charge:
q
z
=
d
12
ab
cos
(
ω
0
t
+
φ
)
q
z
t
=
ω
0
d
12
ab
sin
(
ω
0
t
+
φ
) +
d
12
cos
(
ω
0
t
+
φ
)
(
ab
)
t
≈−
ω
0
d
12
ab
sin
(
ω
0
t
+
φ
)
q
2
z
t
2
ω
2
0
d
12
ab
cos
(
ω
0
t
+
φ
)
,
(20)
where the approximation arises because we will only consider situations where the coefficients
a
and
b
change slowly with time over a large number of cycles of the transition frequency:
(
(
ab
)
t

ab
ω
0
)
.
The motion of the electron mass density endows the electron with a momentum
~
p
:
~
p
=
m
~
v
p
z
=
m
z
t
≈−
m
q
ω
0
d
12
ab
sin
(
ω
0
t
+
φ
)
.
(21)
6. Atom in an Applied Field
Schrödinger had a detailed physical picture of the wave function, and he gave an elegant derivation
of the process underlying the change of atomic state mediated by electromagnetic coupling.
7
Instead of directly tackling the transfer of energy between two atoms, he considered the response of a
single atom to a small externally applied vector potential field
~
A
. He found that the immediate effect of an
applied vector potential is to change the momentum
p
of the electron wave function:
p
z
=
m
z
t
q A
z
p
z
t
=
m
2
z
t
2
q
A
z
t
.
(22)
So the quantity
q
A
z
t
acts as a
force
, causing an
acceleration
of the electron wave function.
This is the physical reason that
A
z
t
can be treated as an
electric field
E
z
8
.
E
z
=
A
z
t
.
(23)
In the simplest case, the
q A
z
term makes only a tiny perturbation to the momentum over a single cycle of
the
ω
0
oscillation, so its effects will only be appreciable over many cycles.
7
The original derivation[
13
] p.137, is not nearly as readable as that in Schrödinger ’s second and third 1928 lectures[
14
], where the
state transition is described in section 9 starting at the bottom of page 31, for which the second lecture is preparatory. There he
solved the problem more generally, including the effect of a slight detuning of the field frequency from the atom’s transition
frequency.
8
Far from an overall charge-neutral charge distribution like an atom, the longitudinal gradient of the scalar potential just cancels
the longitudinal component of
~
A
/
t
, so what is left is
~
E
=
A
/
t
, which is purely transverse.
12 of 34
We consider an additional simplification, where the frequency of the applied field is exactly equal to the
transition frequency
ω
0
of the atom:
A
z
=
A
cos
(
ω
t
)
⇒ −
A
z
t
=
E
z
=
ω
0
A
sin
(
ω
0
t
)
.
(24)
In such evaluations we need to be very careful to identify
exactly which energy
we are calculating:
The electric field is merely a bookkeeping device to keep track of the energy that an electron in one atom
exchanges with another electron in another atom, in such a way that the total energy is conserved. We will
evaluate how much energy a given electron gains from or loses to the field, recognizing that the negative
of that energy represents work done by the electron on the source electron responsible for the field. The
force on the electron is just
q
E
z
. Because
E
z
=
ω
0
A
sin
(
ω
0
t
)
, for a stationary charge, the force is in the
+
z
direction as much as it is in the
z
direction, and, averaged over one cycle of the electric field, the work
averages to zero. However, if the charge itself oscillates with the electric field, it will gain energy
E
from
the work done by the field on the electron over one cycle:
E
cycle
=
q
E
z
dz
=
2
π
/
ω
0
0
q
E
z
z
t
dt
,
(25)
where
z
is the
z
position of the electron center of charge from Eq. 19.
When the electron is "coasting downhill"
with
the electric field, it gains energy and
E
is positive. When
the electron is moving "uphill"
against
the electric field, the electron loses energy and
E
is negative.
As long as the energy gained or lost in each cycle is small compared with
E
0
, we can define a
continuous
power
(rate of change of electron energy), which is understood to be an average over many
cycles. The time required for one cycle is
2
π
ω
0
, so Eq. 25 becomes:
E
t
=
ω
0
E
2
π
=
ω
0
2
π
2
π
/
ω
0
0
q
E
z
z
t
dt
=
1
2
π
2
π
0
q
E
z
z
t
d
(
ω
0
t
)
.
(26)
7. Electromagnetic Coupling
Because our use of electromagnetism is conceptually quite different from that in traditional Maxwell
treatments, we review here the foundations of that discipline from the present perspective.
9
The entire
content of Maxwell’s Equations is contained in the relativistically correct Riemann–Sommerfeld differential
form:
(
2
2
t
2
)
A
=
μ
0
J
,
(27)
where
A
= [
~
A
,
V
]
is the four-potential and
J
= [
~
J
,
ρ
]
is the four-current,
~
A
is the vector potential,
V
is the
scalar potential,
~
J
is the physical current density (no displacement current) and
ρ
is the physical charge
density, all expressed in the same inertial frame.
Connection with the usual electric and magnetic field quantities
~
E
and
~
B
is as follows:
~
E
=
−∇
~
V
~
A
t
~
B
=
∇×
~
A
.
(28)
9
A more detailed discussion from the present viewpoint is given in reference[11].
The standard treatment is given in Jackson Chapter 8[15].
13 of 34
So, once we have the four-potential
A
we can derive any electromagnetic coupling we wish.
Eq. 27 has a completely general Green’s Function solution for the four-potential
A
(
t
)
at a point in space,
from four-current density
J
(
~
r
,
t
)
in volume element
d
vol at at distance
r
=
|
~
r
|
from that point:
A
(
t
) =
μ
0
4
π
J
(
r
)
r
t
±
r
c
d
vol,
(29)
where
r
is the distance from element
d
vol to the point where
A
is evaluated.
The second-order nature of derivatives in Eq. 27 do not favor any particular sign of space or time. Eq. 29
can be expressed in terms of more familiar E&M quantities:
~
A
(
t
) =
μ
0
4
π
~
J
(
r
)
r
t
±
r
c
d
vol
V
(
t
) =
μ
0
4
π
c
2
ρ
(
r
)
r
t
±
r
c
d
vol.
(30)
If the charge density occurs as a small, unified "cloud", as is the case for the wave function of an atomic
electron, and the motion of the wave function is non-relativistic, the
~
J
integral just becomes the movement
of the center of charge:
~
A
(
t
)
μ
0
4
π
ρ
~
v
(
r
)
r
t
±
r
c
d
vol
μ
0
4
π
q
~
v
r
t
±
r
c
.
(31)
Then, from a distance large compared to the size of the wave function,
r
can be taken from the time-average
center of charge, and, as we have chosen previously, the motion is in the
z
direction:
A
z
q
μ
0
4
π
z
r
t
t
±
r
c
.
(32)
If, in addition, the time-average center of charge is stationary relative to the point where
A
z
is measured:
A
z
q
μ
0
4
π
r
z
t
t
±
r
c
.
(33)
It is this form that we shall use for the simple examples presented.
An important difference between standard Maxwell E&M practice and our use of the of the
four-potential to couple atomic wave functions is highlighted by Wheeler and Feynman[5]:
There is no such concept as "the" field,
an independent entity with degrees of freedom of its own.
The field is simply a convenient bookkeeping device for keeping track of the total effect of an arbitrary
number of charges on a particular charge at some position in space. The fact that the field is "radiating into
space" does not imply that it is carrying energy with it. Energy is only transferred at the position of another
charge. Since all charges are the finite charge densities of wave functions, there are no self-energy infinities
in this formulation.
10
The assumption of point-charges has created untold conceptual complications, as
noted above in our discussion of stationary states.
10
Richard Feynman is famously known[
18
] to have abandoned his own WFE because the published version made the assumption
(false and unnecessary[
1
]) that an electric charge does not interact with the field it produces. That assumption was made to
eliminate the self-energy infinities of point-like electrons. However, Feynman later realized that some self-energy was needed to
explain the Lamb shift. Note that no such infinities exist in the present approach because the electron wave function cannot
contract to a point.
14 of 34
Although no energy is carried by "the" field, because it has no degrees of freedom of its own, electrical
engineers have developed extremely clever methods for using it as a bookkeeping method for keeping
track of the energy passing between distant charge distributions by pretending that the energy is carried
in the field. One of the most ingenious is the
Poynting Vector
~
S
, signifying the flow of power (energy per
unit time) per unit area:
~
S
=
1
μ
0
~
~
B
=
1
μ
0
~
A
t
×
(
∇×
~
A
)
.
(34)
We take as an example a z-polarized plane wave of amplitude
A
propagating in the
x
direction:
~
A
=
A
{
0, 0, cos
(
kx
ω
t
)
}
~
E
=
~
A
t
=
A
{
0, 0,
ω
sin
(
kx
ω
t
)
}
~
B
=
∇×
~
A
=
A
{
0,
k
sin
(
kx
ω
t
)
, 0
}
~
S
=
1
μ
0
~
~
B
=
A
2
μ
0
{
k
ω
sin
2
(
kx
ω
t
)
, 0, 0
}
~
S
avg
=
A
2
2
μ
0
{
k
ω
, 0, 0
}
=
A
2
2
μ
0
{
ω
2
c
, 0, 0
}
,
(35)
where the braces signify
{
x
,
y
,
z
}
vectors, and the final form recognizes that, in free space,
kc
=
ω
.
We have ascertained how an atom in a superposed state of two eigenstates can gain or lose energy
from/to an external time-varying vector potential. We are naturally led to ask how much energy an atom
in such a state would radiate into "free space." Far from an overall charge-neutral charge distribution like
an atom, the longitudinal gradient of the scalar potential just cancels the longitudinal component of
~
A
/
t
,
so what is left of the propagating wave is the purely transverse component of the vector potential. Since
the current in the atom is in the
z
direction, the vector potential will be in the
z
direction, but the surviving
propagating field at large distance will be only the transverse component
A
. In a spherical coordinate
system the transverse component of
A
z
will be
A
=
A
sin
(
θ
)
. At large distances, all propagating waves
approach the nature of a plane wave, so we can use Eq. 35 in the form:
S
out
A
2
2
μ
0
ω
2
c
=
A
2
z
sin
2
(
θ
)
2
μ
0
ω
2
c
,
(36)
where
S
out
represents the outward-directed energy flow, whose units look like they are watts per m
3
. But
we must be careful—because of our plane-wave characterization it is only the power propagating in one
direction. So people in the business often give this quantity, called the
radiance
, whose units are watts per
m
3
per steradian. In our simple configuration the atom can be treated as effectively a point source, so the
total power
P
radiated will be just the integral of
S
out
over a spherical surface of radius
r
:
P
π
0
2
π
0
A
2
z
sin
2
(
θ
)
2
μ
0
ω
2
c
r
2
sin
(
θ
)
d
φ
d
θ
=
4
π
r
2
ω
2
A
2
z
3
c
μ
0
.
(37)
15 of 34
From Eq. 20 and Eq. 32, we obtain the vector-potential
A
z
at a distance
r
from the oscillating charge
distribution of our atom, neglecting phase and time delay:
q
z
t
=
ω
0
d
12
a b
sin
(
ω
0
t
)
A
z
q
μ
0
4
π
r
z
t
=
μ
0
ω
0
d
12
4
π
r
a b
sin
(
ω
0
t
)
P
d
2
12
μ
0
ω
4
a
2
b
2
sin
2
(
ω
0
t
)
12
π
c
P
avg
P
rad
a
2
b
2
,
where
P
rad
=
d
2
12
μ
0
ω
4
24
π
c
.
(38)
From the green curve in Fig. 5 we can estimate the dipole matrix element
d
12
, which is
q
times the "length"
between the positive and negative "charge lumps", say
d
12
3
qa
0
. So, for the H atom,
P
rad
2
×
10
9
watt
.
Then from Eq. 17 we find the time course of the radiation process:
E
=
E
0
b
2
E
t
=
P
rad
(
1
b
2
)
b
2
=
E
0
(
b
2
)
t
E
=
E
0
b
2
=
E
0
e
t
/
τ
+
1
where
τ
=
E
0
P
rad
=
̄
h
ω
P
rad
=
24
π
c
̄
h
d
2
12
μ
0
ω
3
7.9
×
10
10
sec.
(39)
In the following two sections we will find that atoms spaced by an arbitrary distance exhibit transactions
of exactly the same form as shown in Fig. 6.
The frequency for this transition is
ω
1.55
×
10
16
/
s
, so in time
τ
there are
2
×
10
6
cycles.
This value justifies our assumption that
a
and
b
change slowly on the time scale of
ω
.
The transition of an excited atom into "empty space" is called
spontaneous emission
, and was the
subject of considerable debate during the early development of QM. It was originally thought that the
spontaneous emission lifetime
τ
, observed as the sharpness of the spectral line, was a local property of each
particular electronic transition. However in 1985 it was observed[
19
] that the lifetime was not fixed and
could be made much longer if the transition occurred in a waveguide beyond cutoff, thereby showing that
the energy from the transition had been propagating outward. This is now widely ascribed to the coupling
of the source electron to degrees of freedom of the radiation field. One widely-held viewpoint treats
the "quantum vacuum" as being made up of an infinite number of quantum harmonic oscillators. The
problem with this view is that each such oscillator would have a zero-point energy that would contribute
to the energy density of space in any gravitational treatment of cosmology. Even when the energies of the
oscillators are cut off at some high value, the contribution of this "dark energy" is 120 orders of magnitude
larger than that needed to agree with astrophysical observations. Such a disagreement between theory
and observation (called the "cosmological constant problem"), even after numerous attempts to reduce it,
is
many orders of magnitude worse than any other theory-vs-observation discrepancy in the history of science
.
The TI does not suffer from this serious defect, since its vacuum has no degrees of freedom of its own.
Where, then, is the radiated energy going? The obvious candidate is the enormous continuum of states
of matter in the early universe, source of the
cosmic microwave background
, to which atoms here and
now are coupled by the quantum handshake. The Poynting vector is just a bookkeeping mechanism for
summing up all the full or partial transitions to matter in that continuum. For independent discussions
from the two of us, see ref.[11] p.94 and ref.[7].
8. Two Coupled Atoms
The central point of this paper is to understand the
photon
mechanism by which energy is transferred
from a
single
excited atom (atom
α
) to another
single
atom (atom
β
) initially in its ground state. We proceed
16 of 34
with the simplest and most idealized case of two identical atoms, where:
(1) Excited atom
α
will start in a state where
b
1 and
a
is very small, but never zero because of its
ever-present random statistical interactions with a vast number of other atoms in the universe, and
(2) Likewise, atom
β
will start in a state where
a
1 and
b
is very small, but never zero for the same
reason.
Thus each atom starts in a two-component state that has an oscillating electrical current described by
Eq. 20:
q
z
α
t
≈−
ω
0
d
12
a
α
b
α
sin
(
ω
0
t
)
q
z
β
t
≈−
ω
0
d
12
a
β
b
β
sin
(
ω
0
t
+
φ
)
,
(40)
where we have taken excited atom
α
as our reference for the phase of the oscillations (
φ
α
=
0),
and the approximation assumes that
a
and
b
are changing slowly on the scale of
ω
0
.
Although that random starting point will contain small excitations of a wide range of phases,
we simplify the problem by assuming the following:
All
of the electric field
E
β
at atom
α
is supplied by atom
β
,
All
of the electric field
E
α
at atom
β
is supplied by atom
α
,
The dipole moments of both atoms are in the
z
direction,
The atoms are separated by a distance
r
in a direction orthogonal to
z
,
The vector potential at distance
r
from a small charge distribution oscillating in the
z
-direction is,
from Eq. 33:
A
z
=
q
μ
0
4
π
r
z
t
t
±
r
c
.
(41)
Since all motions and fields are in the
z
direction, we can henceforth omit the
z
subscript.
When the distance
r
is small compared with the wavelength
r

2
π
c
ω
0
the delay
r
c
can be neglected
11
.
Using Eq. 23 and Eq. 33, the vector potentials and electric fields from the two atoms become:
A
α
q
μ
0
4
π
r
z
α
t
⇒ E
α
=
A
α
t
≈−
q
μ
0
4
π
r
2
z
α
t
2
A
β
q
μ
0
4
π
r
z
β
t
⇒ E
β
=
A
β
t
≈−
q
μ
0
4
π
r
2
z
β
t
2
.
(42)
When atom
α
is subject to electric field
E
β
and atom
β
is subject to electric field
E
α
, the energy of both
atoms will change with time in such a way that the total energy is conserved. Thus the superposition
amplitudes
a
and
b
of both atoms change with time, as described by Eq. 17 and Eq. 26, from which:
E
α
t
1
2
π
2
π
0
q
E
β
z
α
t
d
(
ω
0
t
) =
q
2
μ
0
8
π
2
r
2
π
0
2
z
β
t
2
z
α
t
d
(
ω
0
t
)
E
β
t
1
2
π
2
π
0
q
E
α
z
β
t
d
(
ω
0
t
) =
q
2
μ
0
8
π
2
r
2
π
0
2
z
α
t
2
z
β
t
d
(
ω
0
t
)
.
(43)
11
See footnote for Eq. 23. Since this dimension is of the order of
10
10
m and the wavelength is of the order of
10
7
m, this case can
be accommodated. We shall find that the results we arrive at here are directly adaptable to the centrally important case in which
the atoms are separated by an arbitrarily distance, which will be analyzed in the next section.
17 of 34
From Eq. 43, using the
z
derivatives from Eq. 20:
E
α
t
≈−
μ
0
8
π
2
r
2
π
0
(
ω
2
0
d
12
a
β
b
β
cos
(
ω
0
t
+
φ
)
)(
ω
0
d
12
a
α
b
α
sin
(
ω
0
t
)
d
(
ω
0
t
)
)
≈−
μ
0
ω
3
0
d
2
12
a
β
b
β
a
α
b
α
8
π
2
r
2
π
0
cos
(
ω
0
t
+
φ
)
sin
(
ω
0
t
)
d
(
ω
0
t
) =
μ
0
ω
3
0
d
2
12
a
β
b
β
a
α
b
α
8
π
r
sin
(
φ
)
E
β
t
≈−
μ
0
8
π
2
r
2
π
0
(
ω
2
0
d
12
a
α
b
α
cos
(
ω
0
t
)
)(
ω
0
d
12
a
β
b
β
sin
(
ω
0
t
+
φ
)
d
(
ω
0
t
)
)
≈−
μ
0
ω
3
0
d
2
12
a
α
b
α
a
β
b
β
8
π
2
r
2
π
0
cos
(
ω
0
t
)
sin
(
ω
0
t
+
φ
)
d
(
ω
0
t
) =
μ
0
ω
3
0
d
2
12
a
α
b
α
a
β
b
β
8
π
r
sin
(
φ
)
.
(44)
These equations describe energy transfer between the two atoms in either direction, depending on the
sign of
sin
(
φ
)
. For transfer from atom
α
to atom
β
,
E
α
/
t
is negative. Since this transaction dominated all
competing potential transfers, its amplitude will be maximum, so
sin
(
φ
) =
1. If the starting state had
been atom
β
in the excited (
b
1) state, the sin
(
φ
) = +
1 choice would have been appropriate.
Using :
sin
(
φ
) =
1
and
P
αβ
=
μ
0
ω
3
0
d
2
12
8
π
r
,
(45)
Eq. 44 becomes:
E
α
t
=
E
0
b
2
α
t
=
P
αβ
a
β
b
β
a
α
b
α
E
β
t
=
E
0
b
2
β
t
=
P
αβ
a
α
b
α
a
β
b
β
.
(46)
Energy is conserved by the two atoms during the transfer, and the wave functions are normalized:
E
0
(
b
2
α
+
b
2
β
)
=
E
0
b
2
α
+
b
2
β
=
1
b
β
=
1
b
2
α
a
2
α
+
b
2
α
=
1
a
α
=
1
b
2
α
a
2
β
+
b
2
β
=
1
a
β
=
1
b
2
β
=
b
α
,
(47)
after which substitutions Eq. 46 becomes:
(
b
2
α
)
t
=
g b
2
α
(
1
b
2
α
)
where
g
=
P
αβ
E
0
,
(48)
which has solution:
b
2
α
=
a
2
β
=
1
e
gt
+
1
a
2
α
=
b
2
β
=
1
e
gt
+
1
.
(49)
The direction and magnitude of the entire energy-transfer process is governed by the relative phase
φ
of the electric field and the electron motion in
both atoms
: When the electron motion of
either atom
is
in phase
with the field, the field transfers energy to the electron, and the field is said to
excite
the atom.
When the the electron motion has
opposite phase
from the field, the electron transfers energy "to the field",
and the process is called
stimulated emission
.
Therefore, for the photon transaction to proceed the field from atom
α
must have a phase such that it
"excites" atom
β
, while the field from atom
β
must have a phase such that is absorbs energy and "de-excites"
atom
α
. In the above example, that unique combination occurs when sin
(
φ
) =
1.
18 of 34
-
6
-
4
-
2
0
2
4
6
0.0
0.2
0.4
0.6
0.8
1.0
gt
Figure 6.
Squared state amplitudes for atom
α
:
b
2
α
(blue) and
a
2
α
=
b
2
β
(red) for the Photon transfer of energy
E
0
=
̄
h
ω
0
from atom
α
to atom
β
, from Eq. 49. Using the lower state energy as the zero reference,
E
0
b
2
is
the energy of the state. The green curve shows the normalized power radiated by the atom
α
and absorbed
by atom
β
, from Eq. 48. The optical oscillations at
ω
0
are not shown, as they are normally many orders of
magnitude faster than the transfer time scale
1
/
g
. In the next section we will find that atoms spaced by an
arbitrary distance exhibit transactions of exactly the same form.
The random starting point for the transaction involving one excited atom will contain small excitations
of a wide range of phases. From Eq. 48, the amplitude of each of those excitations will grow at a rate
proportional to its own phase match. Thus the excitation from a random recipient atom that happens to
have
sin
(
φ
)
≈−
1 will win in the race and become the dominant partner in the coordinated oscillation of
both atoms.
Thus, we have identified the source of the intrinsic randomness within quantum mechanics, an aspect
of the theory that has been considered mysterious since its inception in the 1920s.
12
Each wave function will thus evolve its motion to follow the applied field to its maximum resonant
coupling, and we can take
sin
(
φ
) =
1 in these expressions, which we have done in Eq. 46 and Fig. 6.
From a TI point of view, both atoms start in stable states, with each having extremely small admixtures
of the other state, so that both have very small dipole moments oscillating with angular frequency
ω
0
= (
E
2
E
1
)
/ ̄
h
. We assume that in atom
α
this admixture creates an initial positive-energy offer wave
that interacts with the small dipole moment of absorber atom
β
to transfer positive energy, and that in
atom
β
this admixture creates an initial negative-energy confirmation wave from the excited emitter atom
α
that interacts with the small dipole moment of emitter atom
α
to transfer negative energy, as shown
schematically in Fig. 1. Because of these admixtures, both atoms develop small time-dependent dipole
moments that, because of the mixed-energy superposition of states as shown in Fig. 5, oscillate with the
same frequency
ω
0
= (
E
2
E
1
)
/ ̄
h
and act as coupled dipole resonators. The phasing of their resulting
waves is such that energy is transferred from emitter to absorber at a rate that initially rises exponentially,
as shown in Fig. 6.
Energy transferred from one atom to another causes an increase in the minority state of the
superposition, thus increasing the dipole moment of both states and increasing the coupling and, hence, the
12
For the Transactional Interpretation[
1
], this phase selection process clarifies the mechanism by which, in the first stage of
transaction formation, the emitter makes a random choice between competing offer waves arriving from many potential
absorbers. The offer wave with the best phase wins, even if it come from far away. This process also clarifies the "hierarchy"
property of the TI: Among competing offer waves having the correct phase, those originating nearby will have larger initial
amplitudes and will be selected hierarchically over those that originate further away and are therefore weaker by 1/
r
.
19 of 34
rate of energy transfer. This self-reinforcing behavior gives the transition its initial exponential character,
and drives the transaction to its conclusion.
Thus, mutual offer/confirmation perturbations of emitter and absorber acting on each other create a
frequency-matched pair of dipole resonators as two-component superposed states, and this dynamically
unstable system either exponentially avalanches to the formation of a complete transaction, or it disappears
when a competing transaction forms elsewhere.
In a universe full of particles, this process does not occur in isolation, and both emitter and absorber
are also randomly perturbed by waves from other systems that can randomly drive the exponential
instability in either direction. This is the source of the intrinsic randomness in quantum processes. Ruth
Kastner[
16
] describes this intrinsic randomness as "spontaneous symmetry breaking", which perhaps
clarifies the process by analogy with quantum field theory.
We note here that the probability of the transition must depend on two things: the strength of the
electromagnetic coupling between the two states, and the degree to which the wave functions of the initial
states are superposed. The magnitude of the latter must depend on the environment, in which many other
atoms are "chattering" and inducing state-mixing perturbations. Thus, we see the emergence of
Fermi’s
"Golden Rule"[17]
, the assertion that a transition probability in a coupled quantum system depends on
the strength of the coupling and the density of states present to which the transition can proceed. Like the
emergence of the Born Rule from the Transactional Interpretation[
1
], the emergence of Fermi’s Golden
Rule is an unexpected gift delivered to us by the logic of the present formalism.
It is certainly not obvious
a priori
that the Schrödinger recipe for the vector potential in the momentum
(Eq. 22), together with the radiation law from a charge in motion (Eq. 33), would conspire to enable the
composition of the superposed states of two electromagnetically coupled wave functions to reinforce in
such a way that, from the asymmetrical starting state, the energy of one excited atom could
explosively and
completely
transfer to the unexcited atom, as shown in Fig. 6.
If nature had worked a slightly different way, an interaction between those atoms might have resulted
in a different phase, and no full transaction would have been possible. The fact that transfer of energy
between two atoms has this self-reinforcing character makes possible arrangements like a
laser
, where
many atoms in various states of excitation participate in a glorious dance, all participating at exactly the
same frequency and locked in phase.
Why do the signs come out that way?
No one has the slightest idea, but the behavior is so remarkable
that it has been given a name: Photons are classified as
bosons
, meaning that they behave that way!
That remarkable behavior is not due to any "particle" nature of the electromagnetic field, but to the
quantum nature of the states of electrons in atoms, and how the movement of an electron in a superposed
state couples to another such electron electromagnetically. The statistical QM formulation needed some
mechanism to finalize a transaction and did not recognize the inherent positive-feedback that nature built
into a pair of coupled wave functions. Therefore, the founders had to put in wave-function collapse "by
hand", and it has mystified the field ever since.
9. Two Atoms at a Distance
We saw that for two atoms to exchange energy, the field
E
z
at atom
β
must come from atom
α
, the
field
E
z
at atom
α
must come from atom
β
, and the phases of the oscillations must stay in coherent phase
with a particular phase relation during the entire transition.
This phase relation must be maintained even
which the two atoms are an arbitrary distance apart.
This is the problem we now address.
20 of 34
As before, we consider all electron motions and fields in the
z
direction, and drop the
z
subscript. To
be definite, we consider the case where the two atoms are separated along the
x
axis, atom
α
at
x
=
0 in the
excited state and atom
β
at
x
=
r
in its ground state, so their separation
r
is orthogonal to the
z
-directed
current in the atoms. The "light travel time" from atom
α
to atom
β
is thus
t
=
r
/
c
. What is observed is
that the energy radiated by atom
α
at time
t
is absorbed by atom
β
at time
t
+
t
:
E
β
t
t
+
t
=
E
α
t
t
.
(50)
This behavior is familiar from the behavior of a "particle", which carries its own degrees of freedom with
it: It leaves
z
=
0 at time
t
and arrives at
z
=
r
at time
t
+
t
after traveling at velocity
c
. Thus, Lewis’
"photon" became widely accepted as just another particle, with degrees of freedom of its own. We shall see
that this assumption violates a wide range of experimental findings.
For atom
β
, Eq. 43 becomes:
E
β
t
t
+
t
=
1
2
π
2
π
0
q
E
α
(
r
,
t
+
t
)
z
β
t
t
+
t
d
(
t
+
t
)
.
(51)
The retarded field from atom
α
interacts with the motion of the electron in atom
β
. The only difference
from our zero-delay solution is that the energy transfer has its time origin shifted by
t
=
r
/
c
.
This result has required that we choose a
positive
sign for the
±
r
/
c
in Eq. 33. By doing that, we are building
in an "arrow of time", a preferred time direction, in the otherwise even-handed formulation. In particular
we are assuming that the retarded solution transfers positive energy. So far everything is familiar and
consistent with commonly held notions. However
the standard picture leaves no way for atom
α
to lose energy
to atom
β
- It does not conserve energy!
When energy is transferred between two atoms, the field amplitude must be "
coordinate and
symmetrical
" as Lewis described. The field
E
α
(
x
=
r
)
at the second atom due to the current in the
first must be exactly equal in magnitude to the the field
E
β
(
x
=
0
)
at the first atom due to the current in
the second, but separated in time by
t
: For atom
α
, Eq. 43 becomes
E
α
t
t
=
2
π
0
q
E
β
(
x
=
0,
t
)
z
α
t
t
dt
(52)
So the field
E
β
from atom
β
, which arises from the motion of its electron at time
t
+
t
, must arrive at
atom
α
at time
t
,
earlier
than its motion by
t
. The only field that fulfills this condition is the
advanced
field from atom
β
, signified by choosing a negative sign for the
±
r
/
c
in Eq. 33. That choice uniquely
satisfies the requirement for conservation of energy. It also builds complementary "arrows of time" into the
formulation—we assume the advanced solution that transfers negative energy. These two assumptions
create a new "handshake" symmetry that is not expressed in conventional Maxwell E&M.
Once these choices for the
±
r
/
c
in Eq. 33 are made, the resulting equations for each of the energy
derivatives in Eq. 44 are unchanged when
t
+
t
is substituted for
t
in the expression for
E
β
/
t
. So each
transition proceeds in the local time frame of its atom—for all the world as if (except for amplitude) the
other atom were local to it. This "locality on the light cone" is the meaning of Lewis’ comment:
In a pure geometry it would surprise us to find that a true theorem becomes false when the page upon
which the figure is drawn is turned upside down. A dissymmetry alien to the pure geometry of relativity
has been introduced by our notion of causality.
21 of 34
The dissymmetry that concerned Lewis has been eliminated. This conclusion is completely consistent
with the 1909 formulation of Einstein, who was critical of the common practice of simply ignoring the
advanced solutions for electromagnetic propagation:
I regard the equations containing retarded functions, in contrast to Mr. Ritz, as merely auxiliary
mathematical forms. The reason I see myself compelled to take this view is first of all that those forms do
not subsume the energy principle, while I believe that we should adhere to the strict validity of the energy
principle until we have found important reasons for renouncing this guiding star.
After defining the retarded solution as
f
1
, and the advanced solution as
f
2
, he elaborates:
Setting
f
(
x
,
y
,
z
,
t
) =
f
1
amounts to calculating the electromagnetic effect at the point
x
,
y
,
z
from those
motions and configurations of the electric quantities that took place prior to the time point t
.
Setting
f
(
x
,
y
,
z
,
t
) =
f
2
,
one determines the electromagnetic effects from the motions and configurations
that take place after the time point t
.
In the first case the electric field is calculated from the totality of the processes producing it,
and in the second case from the totality of the processes absorbing it...
Both kinds of representation can always be used, regardless of how distant the absorbing bodies are
imagined to be. [22]
The choice of advanced or retarded solution cannot be made
a priori
: It depends upon the
boundary
conditions
of the particular problem at hand. The quantum exchange of energy between two atoms just
happens to require one advanced solution carrying negative energy and one retarded solution carrying
positive energy to satisfy its boundary conditions at the two atoms, which then guarantees the conservation
of energy.
Thus, the even-handed time symmetry of Wheeler-Feynman electrodynamics[
5
,
6
] and of the
Transactional Interpretation of quantum mechanics[
1
], as most simply personified in the two-atom photon
transaction considered here, arises from the symmetry of the electromagnetic propagation equations, with
boundary conditions imposed by the solution of the Schrödinger equation for the electron in each of the
two atoms, as foreseen by Schrödinger. We see that the missing ingredients in previous failed attempts, by
Schrödinger and others, to derive wave function collapse from the wave mechanics formalism were:
1. Advanced waves were not explicitly used as a part of the process.
2.
The self-reinforcing nature of the interaction of two phase-locked wave functions coupled
electromagnetically, which drives the transition to completion, was not appreciated.
To keep in touch with experimental reality, we can estimate the "transition time"
τ
from Eq. 46 and
Eq. 48:
E
β
t
=
P
αβ
a
α
b
α
a
β
b
β
=
μ
0
ω
3
0
d
2
12
8
π
r
a
α
b
α
a
β
b
β
.
(53)
As we did for Eq. 39, from the green curve in Fig. 5 we can estimate the dipole matrix element, which is
q
times the "length" between the positive and negative "charge lumps", say
d
12
3
qa
0
. At the steepest part
of the transition, all the
a
and
b
terms will be 1/
2, so
E
β
t
max
μ
0
ω
3
0
(
3
qa
0
)
2
32
π
r
.
(54)
From any treatment of the hydrogen spectrum we obtain, for the 210
100 transition:
E
0
=
̄
h
ω
0
=
9
q
2
128
πe
0
a
0
,
(55)