Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published December 6, 2006 | Supplemental Material
Journal Article Open

Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET


A trifurcated template, containing three secondary dialkylammonium ion recognition sites for encirclement by a dibenzo [24]crown-8-containing acyclic diene, is used to promote acyclic diene metatheses (ADMET) catalyzed by ruthenium−alkylidene complexes, affording a cyclic trimer in 55% yield. Following this one-step, threefold ADMET reaction, the resulting cyclic trimer was isolated by preparative HPLC and characterized by NMR spectroscopy and mass spectrometry.

Additional Information

© 2006 American Chemical Society. Received August 1, 2006. Publication Date (Web): November 9, 2006. We thank the office of Naval Research (ONR) for supporting this research through the Multidisciplinary University Research Initiative (MURI) program.

Attached Files

Supplemental Material - ja065572jsi20061013_112041.pdf


Files (667.7 kB)
Name Size Download all
667.7 kB Preview Download

Additional details

August 19, 2023
October 25, 2023