Chemical Environment Selectivity in Mössbauer Diffraction from 57Fe3Al

Mössbauer diffraction was used to measure different autocorrelation functions for 57Fe atoms in different chemical environments. The sample was polycrystalline 57Fe3Al with the ordered DO3 structure. Diffraction peaks from a fcc structure with a doubled unit cell were detected when the incident radiation was tuned to the Mössbauer resonance of the Wyckoff 4(b) Fe site, but not for tuning to the 8(c) site, thereby distinguishing the spatial arrangements of these two Fe sites.