Published February 5, 2001
| Supplemental Material
Journal Article
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Reaction of Diazoalkanes with Iron Phosphine Complexes Affords Novel Phosphazine Complexes
- Creators
- Louie, Janis
-
Grubbs, Robert H.
Abstract
The crystal structures of novel products from the insertion of various diazoalkanes into the iron−phosphorus bond in FeCl_2L_2 (L = phosphine) complexes are presented. Specifically, ethyl diazoacetate and diphenyldiazomethane reacted with FeCl_2(PMe_2Ph)_2 to afford FeCl_2[N(PMe_2Ph)NC(H)CO_2Et]_2 (1) and FeCl_2[N(PMe_2Ph)NCPh_2] (2). Interestingly, ethyl diazoacetate inserted into both iron phosphine bonds of FeCl_2(d^ippe)_2 to afford the seven-membered metallacycle FeCl_2{N[NC(H)CO_2Et]P^iPr)_2CH_2CH_2P(^iPPr)_2N[NC(H)CO_2Et]}_2 (3).
Additional Information
© 2001 American Chemical Society. Received 10 July 2000. Published online 6 January 2001. Published in print 1 February 2001. J.L. gratefully acknowledges the National Institutes of Health for a Postdoctoral Fellowship. In addition, we thank crystallographers Lawrence M. Henling and Michael Day.Attached Files
Supplemental Material - om000586y_s.pdf
Supplemental Material - om000586y_sa.pdf
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Additional details
- Eprint ID
- 79903
- Resolver ID
- CaltechAUTHORS:20170808-073454266
- NIH Postdoctoral Fellowship
- Created
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2017-08-09Created from EPrint's datestamp field
- Updated
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2021-11-15Created from EPrint's last_modified field