of 2
Date
Type
n
Sample
spec #'s
δ
47
δ
47
Δ
47, unc
Δ
47, unc
δ
48
Δ
48
Δ
47, HG corr
Δ
47, HG corr
Δ
47
,ACID Corr
*
Δ
47, STD Corr
Δ
47
Δ
47, STD Corr
Δ
47,
ARF
Caltech Temp
ARF Temp
ARF Temp
ID
(‰, WG)
1
s.e.
(‰, WG)
1
s.e.
(‰, WG)
(‰, WG)
(‰, HG)
(‰, HG)
(‰, HG)
(‰, STD)
(‰, HG)
1
s.e.
(‰)
Ghosh
Ghosh
Dennis
unstretched
stretched
stretched
accepted, 25C
(°C)
(°C)
(°C)
SS9 - August, 2009 (manual processing, Caltech MS1, acid digestion @ 25°C, standard corrected and ARF adjusted using CM05)
08/04/09
heated gas
8
Heated Mix
2581
9.433
0.007
-0.720
0.008
42.19
7.498
-0.002
-0.002
N.A.
0.000
0.020
08/06/09
heated gas
8
Heated EBOC
2613
25.28
0.010
-0.557
0.009
80.27
14.17
0.011
0.011
N.A.
0.000
0.034
08/07/09
heated gas
8
Heated BOC
2645
-2.695
0.006
-0.809
0.006
11.98
2.137
0.025
0.026
N.A.
0.000
0.025
08/10/09
standard
8
CM05
2669
20.05
0.009
-0.275
0.009
36.18
6.747
0.342
0.358
N.A.
0.371
0.371
0.028
0.409
116.0
118.9
283.1
08/11/09
heated gas
8
Heated BOC
2685
-2.667
0.010
-0.853
0.010
12.47
2.507
-0.019
-0.020
N.A.
0.000
0.026
08/11/09
heated gas
8
Heated EBOC
2709
22.91
0.009
-0.599
0.008
75.77
13.57
-0.009
-0.009
N.A.
0.000
0.031
08/12/09
heated gas
8
Heated Mix
2717
10.86
0.008
-0.709
0.006
43.86
7.520
-0.005
-0.005
N.A.
0.000
0.020
08/12/09
sample
7
UT-07-44
2733
2.725
0.007
-0.246
0.006
19.06
4.611
0.536
0.561
N.A.
0.574
0.021
0.622
42.4
45.3
57.8
08/12/09
sample
8
UT-07-44
2743
2.702
0.004
-0.253
0.005
18.71
4.297
0.529
0.553
N.A.
0.567
0.020
0.615
44.4
47.3
61.8
08/12/09
heated gas
8
Heated Mix
2751
-9.865
0.010
-0.916
0.010
3.739
0.869
-0.014
-0.014
N.A.
0.000
0.034
SS10 - January, 2010 (autoline, Caltech MS2, acid digestion @ 90°C, standard corrected and ARF adjusted using CM05, NBS-19 and Hagit Carrera)
2010-1-14
heated gas
8
Heated EBOC
396
22.62
0.017
-0.179
0.010
114.5
52.50
-0.002
-0.002
-0.002
0.000
0.011
2010-1-16
heated gas
8
Heated EBOC
538
24.04
0.011
-0.130
0.011
119.3
54.83
0.011
0.012
0.012
0.000
0.012
2010-1-18
heated gas
7
Heated EBOC
645
22.39
0.018
-0.184
0.007
114.8
52.37
-0.001
-0.001
-0.001
0.000
0.009
2010-1-18
standard
8
NBS-19
653
17.68
0.017
-0.055
0.010
46.75
22.10
0.247
0.278
0.359
0.351
0.352
0.011
0.389
126.3
128.8
338.1
2010-1-19
sample
8
UT-07-47
669
0.070
0.012
-0.300
0.007
21.27
10.26
0.450
0.506
0.587
0.578
0.010
0.617
41.4
46.6
60.4
2010-1-19
sample
8
NV-07-109
702
2.892
0.021
-0.160
0.010
8.019
3.946
0.518
0.583
0.664
0.655
0.011
0.695
22.9
28.4
26.6
2010-1-19
heated gas
8
Heated BOC
710
-2.975
0.016
-0.820
0.011
18.03
8.650
0.007
0.008
0.008
0.000
0.013
2010-1-19
standard
6
CM05
719
18.34
0.035
-0.005
0.013
49.38
23.55
0.281
0.316
0.397
0.389
0.371
0.014
0.427
107.3
110.7
244.8
2010-1-20
heated gas
8
Heated BOC
772
-2.561
0.016
-0.827
0.011
20.32
9.962
-0.010
-0.011
-0.011
0.000
0.013
2010-1-20
standard
8
CM05
780
18.38
0.011
-0.028
0.014
50.03
24.06
0.257
0.289
0.370
0.361
0.371
0.015
0.399
120.9
123.7
308.0
2010-1-21
sample
8
UT-07-47
812
0.189
0.021
-0.290
0.018
22.59
11.37
0.457
0.513
0.594
0.586
0.019
0.625
39.4
44.6
56.5
2010-1-21
heated gas
8
Heated EBOC
829
25.42
0.015
-0.113
0.012
126.8
58.65
-0.008
-0.009
-0.009
0.000
0.014
2010-1-22
standard
8
CM05
846
18.24
0.017
-0.028
0.010
49.38
23.66
0.260
0.292
0.373
0.365
0.371
0.011
0.403
118.9
121.8
297.9
2010-1-22
heated gas
8
Heated BOC
904
-2.535
0.011
-0.814
0.008
19.68
9.388
0.003
0.003
0.003
0.000
0.011
2010-1-23
standard
7
Hagit Carrara
941
18.34
0.016
-0.033
0.010
47.56
22.23
0.253
0.285
0.366
0.357
0.352
0.011
0.395
122.9
125.6
319.0
2010-1-24
heated gas
7
Heated BOC
968
-2.975
0.010
-0.836
0.008
17.50
8.363
-0.009
-0.010
-0.010
0.000
0.011
2010-1-24
sample
8
NV-07-109
976
2.953
0.011
-0.166
0.012
8.378
4.180
0.511
0.574
0.655
0.647
0.013
0.686
24.7
30.2
29.8
2010-1-24
sample
8
NV-07-109
1010
2.997
0.009
-0.175
0.009
8.251
3.850
0.501
0.563
0.644
0.636
0.011
0.675
27.3
32.8
34.3
SS11a - June 2010 (autoline, Caltech MS2, acid digestion @ 90°C, standard corrected and ARF adjusted using Hagit Carrera and Carmel Chalk)
2010-5-31
standard
7
CM05
6272
18.09
0.009
-0.071
0.011
45.18
19.94
0.262
0.295
0.376
0.385
0.371
0.012
0.424
109.4
112.2
251.2
2010-5-31
sample
7
UT-07-28-1
6280
1.215
0.012
-0.285
0.008
23.91
10.72
0.438
0.493
0.573
0.581
0.010
0.637
40.7
41.6
50.7
2010-5-31
sample
7
UT-07-28-2
6288
1.119
0.012
-0.268
0.013
23.71
10.40
0.457
0.514
0.594
0.602
0.015
0.660
35.2
36.1
40.3
2010-6-1
sample
7
UT-07-28-2sp
6296
-1.343
0.011
-0.301
0.009
12.38
5.468
0.481
0.541
0.621
0.630
0.012
0.690
28.7
29.4
28.5
2010-6-1
sample
7
UT-07-35-1
6304
0.361
0.011
-0.288
0.012
21.27
9.281
0.455
0.512
0.592
0.600
0.013
0.658
35.8
36.7
41.4
2010-6-1
sample
7
UT-07-28-1
6312
1.076
0.018
-0.284
0.014
23.09
9.968
0.442
0.498
0.578
0.586
0.016
0.642
39.5
40.3
48.3
2010-6-1
sample
7
UT-07-28-2
6321
1.141
0.018
-0.242
0.023
23.44
10.08
0.482
0.543
0.623
0.631
0.024
0.692
28.4
29.1
27.8
2010-6-1
standard
7
CM05
6331
18.07
0.012
-0.090
0.012
44.00
18.77
0.244
0.274
0.355
0.363
0.371
0.014
0.401
119.8
122.9
303.7
2010-6-1
heated gas
7
Heated BOC
6339
-2.784
0.015
-0.848
0.008
16.47
6.834
-0.034
-0.038
-0.038
2010-6-1
standard
7
CM05
6357
18.09
0.014
-0.064
0.016
43.90
18.67
0.269
0.303
0.384
0.392
0.371
0.017
0.431
106.1
108.7
236.4
2010-6-2
sample
7
NV-07-119
6373
8.686
0.012
-0.066
0.010
23.56
10.27
0.484
0.545
0.625
0.633
0.012
0.694
27.8
28.5
26.9
2010-6-2
sample
7
UT-07-28-2sp
6385
-1.355
0.016
-0.333
0.009
12.25
5.218
0.449
0.505
0.585
0.594
0.012
0.651
37.5
38.3
44.5
2010-6-2
sample
8
UT-07-35-1
6395
0.402
0.007
-0.292
0.006
20.79
8.732
0.450
0.506
0.586
0.595
0.009
0.652
37.2
38.1
44.0
2010-6-2
sample
7
NV-07-109-sp
6403
-6.798
0.014
-0.473
0.014
-26.79
-12.01
0.434
0.489
0.569
0.577
0.016
0.633
41.7
42.6
52.6
2010-6-2
sample
8
NV-07-119
6413
8.704
0.010
0.010
0.009
23.28
10.09
0.560
0.630
0.710
0.718
0.011
0.787
10.0
10.4
-2.6
2010-6-2
heated gas
8
Heated EBOC
6422
27.26
0.012
-0.133
0.010
122.0
49.76
-0.011
-0.013
-0.013
2010-6-3
standard
8
Carmel Chalk
6431
11.71
0.007
0.020
0.005
35.92
15.50
0.501
0.564
0.645
0.653
0.644
0.008
0.715
23.4
24.0
19.2
2010-6-3
sample
8
NV-07-110
6440
5.261
0.012
-0.121
0.012
8.105
3.634
0.508
0.572
0.652
0.660
0.013
0.723
21.9
22.5
16.7
2010-6-3
sample
8
NV-07-111
6449
0.780
0.013
-0.276
0.012
-7.104
-2.968
0.457
0.514
0.594
0.602
0.014
0.661
35.2
36.1
40.3
2010-6-3
sample
8
UT-07-41-1(A)
6458
4.171
0.009
-0.201
0.009
21.29
9.187
0.453
0.510
0.590
0.598
0.011
0.656
36.3
37.2
42.3
2010-6-3
sample
8
UT-07-41-1sp
6467
2.184
0.011
-0.237
0.010
16.66
7.347
0.463
0.521
0.601
0.610
0.012
0.668
33.5
34.3
37.1
2010-6-3
sample
7
NV-07-110
6478
5.246
0.015
-0.128
0.015
7.671
3.242
0.501
0.565
0.645
0.653
0.017
0.715
23.5
24.1
19.3
2010-6-3
heated gas
7
Heated BOC
6487
-2.606
0.015
-0.826
0.016
17.24
7.159
-0.016
-0.018
-0.018
2010-6-4
sample
8
NV-07-111
6497
0.758
0.009
-0.264
0.008
-7.201
-3.021
0.469
0.528
0.608
0.617
0.010
0.676
31.8
32.6
34.0
2010-6-4
standard
7
Hagit Carrara
6520
18.25
0.013
-0.059
0.013
44.43
19.30
0.270
0.304
0.385
0.393
0.352
0.014
0.433
105.3
107.9
232.8
2010-6-4
sample
8
UT-07-45 cement
6529
-2.777
0.014
-0.413
0.016
5.871
2.555
0.401
0.452
0.532
0.540
0.018
0.593
51.9
53.1
73.7
2010-6-4
sample
8
UT-07-41 cement
6538
2.638
0.013
-0.232
0.010
18.97
8.451
0.458
0.516
0.596
0.604
0.012
0.662
34.9
35.7
39.7
2010-6-4
sample
8
UT-07-41-1(B)
6547
3.991
0.010
-0.172
0.009
21.30
9.202
0.487
0.548
0.628
0.636
0.011
0.697
27.2
27.8
25.7
2010-6-4
sample
8
UT-07-41-1sp
6558
2.194
0.011
-0.237
0.010
16.52
7.246
0.463
0.522
0.602
0.610
0.012
0.668
33.5
34.3
37.0
2010-6-5
hg
7
Heated EBOC
6567
26.67
0.011
-0.150
0.010
120.1
49.05
-0.015
-0.017
-0.017
2010-6-5
sample
7
UT-07-41 cement
6612
2.593
0.011
-0.239
0.012
18.89
8.449
0.451
0.508
0.588
0.596
0.014
0.654
36.8
37.6
43.1
2010-6-6
standard
7
Carmel Chalk
6621
11.73
0.011
0.016
0.011
35.95
15.53
0.496
0.559
0.640
0.648
0.644
0.012
0.710
24.6
25.2
21.2
2010-6-6
sample
8
NV-07-119
6630
8.537
0.010
-0.048
0.011
23.15
10.20
0.506
0.569
0.649
0.658
0.012
0.720
22.4
23.0
17.6
2010-6-6
sample
8
UT-07-40-1sp
17
-5.416
0.011
-0.499
0.014
0.713
0.408
0.377
0.425
0.505
0.513
0.016
0.563
60.3
61.6
92.4
2010-6-6
sample
7
UT-07-40-1
26
1.002
0.008
-0.265
0.008
19.95
8.657
0.462
0.521
0.601
0.609
0.010
0.667
33.7
34.5
37.5
2010-6-6
hg
7
Heated BOC
6641
-2.716
0.010
-0.829
0.009
17.12
7.008
-0.016
-0.018
-0.018
2010-6-7
sample
8
UT-07-26-1
6668
0.911
0.006
-0.277
0.006
22.35
9.800
0.452
0.509
0.589
0.597
0.009
0.655
36.5
37.3
42.6
2010-6-7
standard
8
CM05
6677
17.95
0.012
-0.109
0.010
43.28
18.29
0.227
0.255
0.336
0.344
0.371
0.012
0.380
129.9
133.3
367.5
SS11b - June 2010 (autoline, Caltech MS1, acid digestion @ 90°C, standard corrected and ARF adjusted using Hagit carrera)
06/01/10
standard
8
Carmel Chalk
876
11.22
0.011
-0.197
0.011
23.78
4.059
0.515
0.548
0.629
0.644
0.644
0.016
0.713
25.5
24.4
19.9
06/02/10
heated gas
8
Heated EBOC
38
26.29
0.017
-0.597
0.015
81.47
12.80
0.004
0.004
0.004
06/04/10
standard
8
Hagit Carrara
63
17.58
0.016
-0.412
0.011
28.90
4.720
0.253
0.269
0.350
0.365
0.352
0.017
0.409
119.2
119.1
283.9
2010-6-8
standard
7
Hagit Carrara
112
17.67
0.008
-0.415
0.007
29.01
4.677
0.250
0.266
0.347
0.361
0.352
0.014
0.405
120.9
120.9
292.9
2010-6-8
sample
7
UT-07-26-1
123
0.707
0.012
-0.276
0.012
14.86
2.791
0.514
0.547
0.628
0.642
0.019
0.712
25.8
24.8
20.5
2010-6-8
sample
7
NV-07-112sp
131
-0.897
0.012
-0.318
0.012
-25.31
-3.317
0.484
0.514
0.595
0.610
0.020
0.677
33.4
32.4
33.7
2010-6-8
heated gas
8
Heated BOC
139
-3.535
0.013
-0.829
0.012
10.63
2.543
-0.008
-0.008
-0.008
2010-6-14
sample
5
NV07-112 billet 2
149
6.746
0.008
-0.211
0.008
4.192
0.994
0.534
0.568
0.649
0.663
0.015
0.735
21.2
20.1
12.8
2010-6-14
sample
8
NV07-117 billet 1
160
12.81
0.011
-0.183
0.010
23.03
4.304
0.518
0.550
0.631
0.646
0.016
0.716
25.0
23.9
19.1
2010-6-14
sample
8
UT07-43-1
170
0.202
0.011
-0.306
0.009
13.00
3.370
0.487
0.518
0.599
0.614
0.018
0.681
32.4
31.4
31.9
2010-6-15
sample
7
UT07-28-2
181
0.793
0.007
-0.279
0.007
15.64
3.004
0.511
0.543
0.624
0.639
0.016
0.708
26.7
25.6
21.9
2010-6-15
standard
6
Carmel Chalk
189
11.19
0.006
-0.205
0.006
23.98
4.322
0.507
0.540
0.621
0.635
0.644
0.013
0.704
27.4
26.4
23.3
2010-6-15
sample
8
NV-07-117
202
12.98
0.006
-0.180
0.005
24.08
5.003
0.520
0.553
0.634
0.648
0.013
0.718
24.5
23.4
18.3
2010-6-16
sample
7
NV-07-112
216
6.859
0.009
-0.219
0.009
4.728
1.204
0.525
0.558
0.639
0.654
0.015
0.724
23.2
22.2
16.2
2010-6-16
sample
7
UT-07-43-1
224
0.095
0.014
-0.334
0.015
11.51
2.118
0.460
0.489
0.570
0.585
0.021
0.649
39.8
38.8
45.4
2010-6-16
heated gas
8
Heated EBOC
241
25.91
0.015
-0.607
0.013
81.38
13.57
-0.003
-0.003
-0.003
06/22/10
standard
8
Carmel Chalk
270
11.32
0.011
-0.187
0.009
23.96
4.073
0.524
0.557
0.638
0.653
0.644
0.015
0.723
23.5
22.4
16.5
06/22/10
standard
8
Hagit Carrara
302
17.70
0.011
-0.422
0.008
29.32
4.876
0.242
0.258
0.339
0.353
0.352
0.015
0.397
125.0
125.0
315.3
06/24/10
hg
8
BOC
357
-4.153
0.013
-0.814
0.010
9.357
1.884
0.011
0.012
0.012
SS12 - February-March 2011 (autoline, Caltech MS2, acid digestion at 90°C, moving heated gas line processing; ARF adjusted using Hagit Carrera and TV01)
2011-2-28
heated gas
8
Heated EBOC
699
20.815
0.011
-0.295
0.010
90.78
34.383
0.0098
0.0098
0.0098
2011-2-28
standard
8
Hagit Carrara
727
17.943
0.013
-0.1
0.012
41.675
17.108
0.2746
0.279
0.36
0.3504
0.352
0.020
0.405
126.6
120.9
293.2
2011-2-28
heated gas
8
Heated BOC
736
-4.662
0.019
-0.974
0.017
12.08
4.974
-0.0166
-0.0166
-0.0166
2011-2-28
standard
8
TV01
745
11.383
0.016
0.052
0.015
19.103
8.434
0.5945
0.6033
0.6843
0.6755
0.662
0.020
0.749
18.6
17.4
8.4
2011-2-28
standard
8
TV01
754
11.297
0.017
0.011
0.016
18.695
8.008
0.5552
0.563
0.644
0.6358
0.662
0.021
0.707
27.3
25.9
22.3
2011-3-1
standard
8
Hagit Carrara
763
17.989
0.026
-0.106
0.024
43.147
18.44
0.263
0.2665
0.3475
0.3398
0.352
0.029
0.394
132.5
126.4
323.6
2011-3-1
heated gas
8
Heated EBOC
773
18.613
0.012
-0.364
0.011
93.585
39.574
-0.0125
-0.0125
-0.0125
2011-3-1
standard
8
Hagit Carrara
783
18.009
0.026
-0.077
0.024
45.248
20.505
0.2892
0.2927
0.3737
0.3673
0.352
0.029
0.423
117.8
112.6
253.1
2011-3-2
standard
8
TV01
792
11.348
0.020
0.044
0.019
20.498
9.805
0.585
0.5915
0.6725
0.6668
0.662
0.023
0.739
20.4
19.2
11.3
2011-3-2
sample
7
NV-07-119
802
8.237
0.013
-0.058
0.012
22.85
10.436
0.5649
0.5708
0.6518
0.6469
0.017
0.718
24.8
23.4
18.2
2011-3-2
sample
8
UT-07-40
810
0.761
0.017
-0.319
0.016
19.114
8.268
0.5025
0.5074
0.5884
0.5842
0.022
0.652
39.9
38.0
43.9
2011-3-2
sample
8
UT-07-41-1
819
3.837
0.012
-0.204
0.012
21.328
9.659
0.536
0.5408
0.6218
0.6184
0.018
0.688
31.4
29.8
29.1
2011-3-2
heated gas
8
Heated BOC
5
-3.299
0.014
-0.954
0.013
16.254
6.917
-0.0227
-0.0227
-0.0227
2011-3-3
standard
8
TV01
16
11.291
0.009
0.034
0.010
19.73
9.08
0.5741
0.5785
0.6595
0.6577
0.662
0.016
0.730
22.4
21.1
14.4
2011-3-3
sample
8
UT-07-43-1
34
0.024
0.016
-0.354
0.015
18.46
9.07
0.4901
0.4932
0.5742
0.5741
0.021
0.641
42.5
40.6
48.7
2011-3-3
sample
8
UT-07-26-1
43
0.633
0.013
-0.309
0.013
23.798
11.735
0.5192
0.522
0.603
0.6038
0.019
0.673
34.9
33.2
35.2
2011-3-3
heated gas
8
Heated EBOC
52
18.117
0.017
-0.353
0.017
101.275
47.363
-0.0009
-0.0009
-0.0009
2011-3-3
standard
8
Hagit Carrara
61
18.025
0.010
-0.083
0.009
48.086
23.209
0.2705
0.2716
0.3526
0.3552
0.352
0.018
0.410
124.1
118.5
280.9
2011-3-4
sample
8
UT-07-44
70
0.903
0.012
-0.315
0.010
19.382
9.044
0.5074
0.5091
0.5901
0.5936
0.018
0.662
37.5
35.7
39.6
2011-3-4
sample
8
UT-07-28-2
79
0.692
0.018
-0.305
0.016
24.351
11.746
0.5237
0.5251
0.6061
0.6105
0.022
0.680
33.3
31.7
32.4
2011-3-4
sample
8
16-92
88
1.222
0.014
-0.327
0.014
8.188
3.827
0.4876
0.4885
0.5695
0.5748
0.020
0.642
42.3
40.4
48.4
2011-3-4
sample
8
UT-07-45 cement
97
-2.282
0.017
-0.459
0.016
6.839
3.202
0.4532
0.4538
0.5348
0.541
0.023
0.606
51.7
49.5
66.2
2011-3-4
heated gas
8
Heated BOC
106
-2.82
0.013
-0.93
0.013
18.807
8.951
-0.002
-0.002
-0.002
2011-3-4
standard
8
TV01
115
11.303
0.014
0.042
0.012
21.192
10.504
0.5765
0.5764
0.6574
0.6654
0.662
0.017
0.738
20.7
19.5
11.8
2011-3-5
sample
8
NV-07-109-sp
124
-7.521
0.013
-0.579
0.012
-33.203
-17.386
0.4825
0.482
0.563
0.5719
0.024
0.639
43.1
41.2
49.8
2011-3-5
sample
7
NV-07-115
142
15.702
0.020
0.133
0.017
36.465
18.329
0.5342
0.533
0.614
0.6246
0.022
0.695
29.9
28.4
26.6
2011-3-5
heated gas
8
Heated EBOC
152
18.053
0.012
-0.327
0.012
103.275
49.878
0.0146
0.0146
0.0146
2011-3-5
standard
8
Hagit Carrara
161
17.942
0.008
-0.084
0.007
50.066
25.298
0.2596
0.2587
0.3397
0.3518
0.352
0.017
0.406
125.9
120.2
289.5
2011-3-6
sample
8
UT-07-44
171
0.378
0.016
-0.311
0.016
21.045
11.204
0.532
0.5296
0.6106
0.6235
0.022
0.694
30.2
28.6
27.1
2011-3-6
sample
8
UT-07-28-2-sp
180
-1.467
0.012
-0.37
0.010
13.213
6.872
0.5263
0.5236
0.6046
0.6182
0.019
0.688
31.4
29.9
29.2
2011-3-6
sample
8
NV-07-112-sp
189
-1.4
0.011
-0.426
0.010
-46.219
-25.197
0.4691
0.4664
0.5474
0.5617
0.019
0.628
45.9
43.8
55.0
2011-3-6
heated gas
8
Heated BOC
207
-2.474
0.011
-0.922
0.011
20.38
9.764
0.0056
0.0056
0.0056
2011-3-6
standard
8
TV01
216
11.406
0.009
0.044
0.010
22.371
11.554
0.5703
0.5658
0.6468
0.663
0.662
0.016
0.735
21.3
20.0
12.6
2011-3-7
sample
8
NV-07-118 (brown)
225
15.856
0.014
0.125
0.015
35.072
17.394
0.5215
0.5171
0.5981
0.6148
0.021
0.684
32.2
30.6
30.6
2011-3-7
sample
8
NV-07-115
234
15.738
0.012
0.142
0.012
38.288
20.137
0.541
0.536
0.617
0.6343
0.019
0.705
27.6
26.2
22.9
2011-3-7
sample
8
UT-07-41-1
243
3.758
0.019
-0.205
0.017
24.336
12.791
0.5436
0.5382
0.6192
0.6369
0.021
0.708
27.1
25.6
21.9
2011-3-7
heated gas
8
Heated EBOC
252
19.334
0.015
-0.299
0.015
110.144
54.995
-0.0073
-0.0073
-0.0073
2011-3-7
standard
8
Hagit Carrara
261
18.043
0.025
-0.057
0.023
50.918
26.017
0.2715
0.2684
0.3494
0.3678
0.352
0.028
0.423
117.6
112.4
252.0
2011-3-7
standard
8
Hagit Carrara
270
17.889
0.014
-0.095
0.011
49.732
25.044
0.2369
0.2341
0.3151
0.3337
0.352
0.019
0.387
136.0
129.7
343.5
2011-3-8
sample
8
UT-07-43-1
279
0.22
0.018
-0.34
0.018
20.063
10.323
0.5144
0.5079
0.5889
0.6077
0.023
0.677
34.0
32.3
33.5
2011-3-8
sample
8
UT-07-26-1
288
0.635
0.019
-0.333
0.017
24.94
12.827
0.5096
0.5028
0.5838
0.6028
0.023
0.672
35.2
33.5
35.6
2011-3-8
sample
8
NV-07-118 (brown)
298
15.901
0.015
0.145
0.014
35.742
18.37
0.532
0.5242
0.6052
0.6243
0.020
0.694
30.0
28.5
26.8
2011-3-8
heated gas
8
Heated BOC
307
-2.937
0.013
-0.928
0.012
20.144
10.279
0.0234
0.0234
0.0234
Table S1: Raw
Δ
47
and
Δ
48
data for all samples, standards and heated gases
SS13 - April, 2011(autoline, Caltech MS2, acid digestion @ 90°C, Standard corrected using TV01, ARF adjusted using TV01 and hagit carrera)
2011-4-11
heated gas
8
Heated BOC
54
-3.986
0.013
-0.945
0.013
15.06
7.320
0.005
0.005
0.005
2011-4-11
standard
8
Hagit Carrara
62
18.19
0.010
-0.051
0.009
55.81
30.54
0.290
0.292
0.373
0.378
0.352
0.015
0.420
112.3
113.7
258.0
2011-4-12
sample
8
NV-07-119
70
8.416
0.018
-0.044
0.018
27.59
14.80
0.565
0.569
0.650
0.655
0.020
0.722
22.9
22.6
16.9
2011-4-12
sample
8
UT-07-41-1
78
3.999
0.024
-0.215
0.023
27.44
15.46
0.516
0.519
0.600
0.606
0.025
0.668
34.4
34.3
37.0
2011-4-12
sample
8
UT-07-40-1
86
0.855
0.011
-0.335
0.007
25.22
14.09
0.482
0.485
0.566
0.572
0.012
0.631
43.2
43.2
53.7
2011-4-12
standard
8
TV01
94
11.16
0.013
0.030
0.013
22.46
11.77
0.564
0.567
0.648
0.654
0.662
0.016
0.721
23.2
22.9
17.3
2011-4-12
sample
8
UT-07-33-1
102
0.995
0.016
-0.321
0.016
25.11
13.55
0.492
0.495
0.576
0.581
0.019
0.641
40.6
40.6
48.7
2011-4-12
sample
8
UT-07-33-1sp
110
-5.300
0.012
-0.511
0.011
0.707
0.203
0.475
0.477
0.558
0.564
0.018
0.623
45.2
45.2
57.7
2011-4-12
heated gas
8
Heated EBOC
118
18.86
0.015
-0.327
0.013
116.3
61.06
-0.005
-0.005
-0.005
2011-4-13
standard
8
Hagit Carrara
126
18.17
0.013
-0.052
0.011
55.81
30.56
0.289
0.291
0.372
0.378
0.352
0.016
0.419
112.8
114.2
260.2
2011-4-13
sample
8
UT-07-28-2
134
0.999
0.017
-0.319
0.017
28.92
15.74
0.494
0.497
0.578
0.584
0.019
0.644
40.0
39.9
47.5
2011-4-13
standard
8
TV01
158
11.45
0.009
0.040
0.009
24.36
13.35
0.567
0.570
0.651
0.656
0.662
0.013
0.724
22.7
22.4
16.5
2011-4-13
sample
8
UT-07-33-1
166
1.014
0.023
-0.335
0.022
25.20
13.55
0.477
0.480
0.561
0.567
0.024
0.626
44.5
44.5
56.3
2011-4-13
heated gas
8
Heated BOC
174
-3.613
0.016
-0.945
0.013
19.61
10.64
-0.005
-0.005
-0.005
2011-4-14
standard
8
TV01
182
11.59
0.018
0.062
0.014
24.24
13.04
0.585
0.588
0.669
0.675
0.662
0.017
0.743
18.8
18.4
10.0
2011-4-14
sample
8
UT-07-33-1sp
190
-5.267
0.014
-0.532
0.013
-0.148
-0.720
0.453
0.456
0.537
0.542
0.019
0.599
51.3
51.4
70.2
2011-4-14
sample
8
NV-07-109-sp
198
-7.583
0.015
-0.583
0.016
-37.05
-21.21
0.465
0.468
0.549
0.555
0.022
0.612
47.8
47.9
63.0
2011-4-14
sample
8
NV-07-110
206
5.136
0.019
-0.153
0.019
9.451
5.138
0.546
0.549
0.630
0.636
0.021
0.701
27.3
27.0
24.3
2011-4-14
heated gas
8
Heated EBOC
222
17.23
0.017
-0.362
0.017
110.9
58.26
0.005
0.005
0.005
2011-4-15
standard
8
Hagit Carrara
230
18.17
0.020
-0.075
0.018
53.99
28.74
0.267
0.268
0.349
0.355
0.352
0.021
0.395
124.2
126.0
320.9
2011-4-15
sample
8
NV-07-111
246
0.624
0.012
-0.349
0.010
-9.841
-5.610
0.475
0.477
0.558
0.564
0.015
0.623
45.3
45.3
57.7
2011-4-15
sample
8
NV-07-115
254
15.91
0.014
0.136
0.014
41.17
22.55
0.539
0.543
0.624
0.629
0.017
0.694
28.8
28.6
27.0
2011-4-15
sample
8
UT-07-41 cement
262
2.778
0.020
-0.289
0.019
22.41
11.76
0.475
0.477
0.558
0.564
0.021
0.623
45.2
45.2
57.6
2011-4-15
sample
8
UT-07-45 cement
270
-2.590
0.029
-0.472
0.018
8.236
4.831
0.440
0.443
0.524
0.529
0.021
0.585
55.2
55.3
78.5
2011-4-15
heated gas
8
Heated BOC
278
-2.793
0.011
-0.929
0.011
22.33
12.36
-0.012
-0.012
-0.012
2011-4-16
standard
8
TV01
286
11.37
0.012
0.044
0.011
25.27
14.35
0.572
0.576
0.657
0.662
0.662
0.014
0.730
21.4
21.1
14.3
2011-4-16
sample
8
UT-07-26-1
294
1.435
0.027
-0.284
0.025
28.04
16.49
0.517
0.520
0.601
0.607
0.027
0.670
34.1
34.0
36.5
2011-4-16
sample
7
UT-07-28-1
302
0.739
0.017
-0.361
0.017
28.68
16.03
0.459
0.462
0.543
0.549
0.020
0.606
49.5
49.6
66.4
2011-4-16
sample
8
UT-07-35-1
310
0.088
0.020
-0.336
0.020
24.64
13.07
0.502
0.505
0.586
0.591
0.022
0.653
38.0
37.9
43.7
2011-4-16
sample
8
NV-07-117
318
13.12
0.015
0.088
0.012
42.04
22.85
0.569
0.572
0.653
0.659
0.015
0.726
22.2
21.9
15.7
2011-4-16
heated gas
8
Heated EBOC
326
19.05
0.012
-0.324
0.011
118.0
62.35
-0.006
-0.006
-0.006
2011-4-16
standard
8
Hagit Carrara
336
18.10
0.020
-0.062
0.020
54.12
29.04
0.282
0.283
0.364
0.370
0.352
0.024
0.411
116.4
117.9
278.0
2011-4-17
sample
8
UT-07-40-1
344
0.915
0.013
-0.321
0.013
24.35
13.16
0.495
0.497
0.578
0.584
0.017
0.645
39.9
39.8
47.3
2011-4-17
sample
8
UT-07-28-1
352
0.816
0.020
-0.343
0.021
27.28
14.56
0.475
0.477
0.558
0.564
0.023
0.623
45.2
45.2
57.6
2011-4-17
sample
8
UT-07-47
360
0.053
0.024
-0.314
0.022
24.42
13.66
0.525
0.528
0.609
0.615
0.024
0.678
32.2
32.0
32.9
2011-4-17
sample
8
UT-07-41 cement
368
2.598
0.024
-0.299
0.023
23.10
12.57
0.470
0.473
0.554
0.559
0.025
0.617
46.5
46.6
60.3
2011-4-17
heated gas
8
Heated EBOC
376
17.76
0.010
-0.346
0.011
111.3
58.48
0.007
0.007
0.007
4/17/11
standard
8
TV01
384
11.62
0.013
0.051
0.012
24.46
13.39
0.572
0.576
0.657
0.662
0.662
0.015
0.730
21.4
21.1
14.4
2011-4-18
sample
8
UT-07-02
392
3.246
0.020
-0.296
0.019
1.477
0.677
0.455
0.458
0.539
0.544
0.021
0.601
50.7
50.8
69.0
2011-4-18
sample
8
NV-07-111
400
0.601
0.014
-0.341
0.013
-10.41
-6.104
0.483
0.486
0.567
0.573
0.017
0.632
42.9
42.9
53.1
2011-4-18
sample
8
NV-07-112
409
7.017
0.019
-0.098
0.013
8.447
4.840
0.550
0.553
0.634
0.639
0.016
0.705
26.5
26.2
22.9
2011-4-18
sample
8
UT-07-28-2
417
1.153
0.014
-0.314
0.012
29.15
15.78
0.495
0.498
0.579
0.584
0.016
0.645
39.8
39.7
47.1
2011-4-18
heated gas
8
Heated BOC
425
-2.607
0.013
-0.898
0.013
21.68
11.64
0.014
0.014
0.014
SS14 - May, 2011 (autoline, Caltech MS1, acid digestion @ 90°C, Standard corrected using TV01, ARF adjusted using TV01 and hagit carrera)
5/15/11
heated gas
8
Heated BOC
669
-3.089
0.007
-0.829
0.012
11.47
2.512
-0.002
-0.002
-0.002
5/16/11
heated gas
8
Heated EBOC
760
19.08
0.005
-0.639
0.007
68.72
14.91
-0.003
-0.003
-0.003
5/18/11
heated gas
8
Heated BOC
877
-3.126
0.007
-0.821
0.007
11.43
2.616
0.006
0.006
0.006
5/18/11
standard
8
TV01
896
11.49
0.006
-0.127
0.007
14.55
3.542
0.575
0.607
0.688
0.655
0.662
0.008
0.723
23.0
22.5
16.6
5/18/11
sample
8
TMA3-2
914
-1.318
0.006
-0.277
0.005
8.435
2.376
0.535
0.565
0.646
0.612
0.007
0.679
32.9
31.8
32.5
5/19/11
standard
8
Hagit Carrara
934
17.82
0.006
-0.357
0.009
32.19
7.664
0.290
0.307
0.388
0.354
0.352
0.010
0.415
124.5
116.2
269.6
5/20/11
sample
8
TMA3-2
997
-1.116
0.005
-0.284
0.008
8.888
2.563
0.526
0.555
0.636
0.603
0.009
0.670
35.2
34.0
36.5
5/20/11
heated gas
8
Heated EBOC
1015
18.95
0.006
-0.644
0.009
69.10
15.66
-0.006
-0.007
-0.007
05/20/11
heated gas
8
Heated BOC
1031
-2.886
0.007
-0.831
0.007
12.25
3.023
-0.005
-0.006
-0.006
5/20/11
standard
8
TV01
1033
11.28
0.004
-0.128
0.010
14.29
3.521
0.575
0.607
0.688
0.655
0.662
0.010
0.723
23.0
22.4
16.6
5/21/11
standard
8
Hagit Carrara
1051
17.68
0.006
-0.358
0.007
32.07
7.727
0.290
0.306
0.387
0.354
0.352
0.008
0.414
124.8
116.5
271.0
5/21/11
heated gas
8
Heated EBOC
1115
18.64
0.006
-0.655
0.011
68.52
15.11
-0.015
-0.016
5/22/11
heated gas
8
Heated EBOC
1171
18.24
0.008
-0.620
0.009
67.77
15.74
0.023
0.025
SS15 - June, 2011 (autoline, Caltech MS2, acid digestion @ 90°C, Standard corrected using TV01, ARF adjusted using TV01 and hagit carrera)
6/06/2011
heated gas
8
Heated BOC
117
-3.448
0.009
-0.902
0.009
12.83
3.888
0.007
0.007
0.007
0.009
6/06/2011
heated gas
8
Heated EBOC
133
18.51
0.005
-0.632
0.020
75.67
22.408
-0.038
-0.038
-0.038
0.020
6/07/2011
standard
8
TV01
141
11.40
0.007
-0.120
0.018
16.10
5.127
0.576
0.567
0.648
0.652
0.662
0.018
0.731
23.7
20.8
13.9
6/07/2011
standard
8
Carmel Chalk
149
11.43
0.014
-0.106
0.016
29.28
9.225
0.589
0.579
0.660
0.665
0.644
0.016
0.745
20.9
18.0
9.4
6/07/2011
standard
8
Hagit Carrara
157
18.00
0.008
-0.323
0.010
36.25
11.301
0.278
0.273
0.354
0.358
0.352
0.010
0.410
122.5
118.2
279.6
6/07/2011
heated gas
8
Heated BOC
167
-3.742
0.008
-0.896
0.010
11.71
3.524
0.017
0.017
0.017
0.010
6/08/2011
heated gas
8
Heated EBOC
199
16.89
0.006
-0.591
0.012
71.45
22.114
0.026
0.025
0.025
0.012
6/08/2011
standard
8
TV01
207
11.46
0.006
-0.119
0.007
16.50
5.438
0.576
0.567
0.648
0.652
0.662
0.007
0.731
23.7
20.8
13.9
6/08/2011
heated gas
8
Heated BOC
231
-3.204
0.007
-0.944
0.014
13.93
4.395
-0.039
-0.038
-0.038
0.014
6/09/2011
sample
6
TMA3-2
263
-1.356
0.008
-0.314
0.007
8.838
2.777
0.565
0.556
0.637
0.641
0.007
0.719
26.2
23.2
17.9
SS16 - June, 2011 (autoline, Caltech MS1, acid digestion @ 90°C, Standard corrected and ARF adjusted using TV01 and hagit carrera)
06/13/11
heated gas
8
Heated EBOC
794
16.803
0.005
-0.606
0.011
67.042
18.427
0.019
0.019
0.019
0.021
06/13/11
standard
8
TV01
803
11.355
0.011
-0.156
0.008
16.108
5.343
0.535
0.545
0.626
0.648
0.662
0.020
0.718
24.5
23.5
18.3
06/13/11
standard
8
Hagit Carrara
812
17.724
0.006
-0.381
0.011
34.747
10.268
0.232
0.237
0.318
0.340
0.352
0.021
0.384
132.4
131.5
355.2
6/14/2011
heated gas
8
Heated BOC
821
-2.598
0.005
-0.868
0.010
13.297
4.058
-0.007
-0.007
-0.007
0.021
06/14/11
heated gas
8
Heated EBOC
855
17.329
0.007
-0.631
0.009
69.122
18.195
-0.013
-0.013
-0.013
0.020
06/14/11
heated gas
8
Heated BOC
864
-3.031
0.007
-0.885
0.009
12.762
3.775
-0.019
-0.019
-0.019
0.020
06/15/11
heated gas
8
Heated EBOC
908
18.494
0.006
-0.601
0.014
70.078
18.393
0.003
0.003
0.084
0.023
06/15/11
standard
8
TV01
928
11.323
0.006
-0.138
0.014
15.208
4.427
0.553
0.563
0.644
0.667
0.662
0.023
0.738
20.5
19.5
11.7
6/16/2011
heated gas
8
Heated BOC
955
-3.704
0.007
-0.863
0.012
10.709
2.917
0.011
0.011
0.011
0.022
06/16/11
heated gas
8
Heated EBOC
984
17.381
0.006
-0.606
0.007
67.561
17.755
0.011
0.011
0.011
0.020
06/17/11
standard
8
TV01
1030
11.323
0.009
-0.113
0.012
15.331
4.507
0.578
0.589
0.670
0.693
0.662
0.022
0.766
15.1
14.1
3.1
06/17/11
heated gas
8
Heated BOC
1040
-3.440
0.006
-0.887
0.007
12.279
3.239
-0.016
-0.016
-0.016
0.020
06/17/11
sample
8
TM Lenoir
1049
-1.176
0.005
-0.330
0.010
7.057
2.135
0.513
0.523
0.604
0.626
0.021
0.694
29.5
28.5
26.8
06/18/11
heated gas
8
Heated EBOC
1095
17.786
0.005
-0.631
0.010
70.983
18.878
-0.018
-0.019
-0.019
0.021
06/19/11
standard
8
Hagit Carrara
1123
17.839
0.005
-0.362
0.007
33.796
9.185
0.250
0.255
0.336
0.358
0.352
0.020
0.403
122.7
121.8
298.0
06/19/11
sample
8
TM "B" Caliche 1
1141
-1.659
0.006
-0.327
0.011
9.278
2.754
0.523
0.533
0.614
0.636
0.021
0.705
27.2
26.2
22.8
06/19/11
heated gas
8
Heated BOC
1161
-2.914
0.004
-0.857
0.010
12.319
3.359
0.008
0.009
0.009
0.021
06/19/11
standard
8
TV01
1173
11.386
0.004
-0.139
0.011
15.422
4.411
0.551
0.562
0.643
0.665
0.662
0.021
0.736
20.8
19.8
12.3
06/20/11
standard
8
TV01
1192
11.270
0.005
-0.161
0.009
14.958
4.143
0.531
0.541
0.622
0.644
0.662
0.020
0.713
25.5
24.4
19.9
SS16 - July, 2011 (autoline, Caltech MS2, acid digestion @ 90°C, Standard corrected and ARF adjusted using TV01 and hagit carrera)
7/18/11
heated gas
8
Heated BOC
532
-2.818
0.007
-0.911
0.013
14.11
4.715
0.008
0.008
0.008
0.019
7/18/11
standard
8
TV01
542
11.44
0.005
-0.073
0.008
17.08
6.097
0.590
0.574
0.655
0.657
0.662
0.014
0.730
22.6
21.0
14.2
7/19/11
standard
8
Carrara Marble
566
17.89
0.006
-0.288
0.013
37.81
13.09
0.260
0.253
0.334
0.335
0.352
0.018
0.382
135.0
132.5
361.4
7/19/11
heated gas
8
Heated EBOC
582
26.69
0.006
-0.392
0.013
105.4
35.18
-0.002
-0.002
-0.002
0.021
7/19/11
sample
8
TM "B" Caliche
598
-1.917
0.008
-0.369
0.014
10.47
3.979
0.534
0.520
0.601
0.602
0.020
0.671
35.3
33.6
35.8
7/19/11
standard
8
TV01
606
11.41
0.005
-0.085
0.010
17.05
6.147
0.579
0.563
0.644
0.646
0.662
0.016
0.718
25.1
23.4
18.3
7/20/2011
sample
8
TM Lenoir 1
614
-1.137
0.007
-0.374
0.017
8.186
3.096
0.515
0.501
0.582
0.584
0.022
0.651
40.0
38.3
44.3
7/20/11
sample
8
TMA3-2
622
-1.283
0.007
-0.326
0.012
9.723
3.533
0.565
0.550
0.631
0.633
0.018
0.704
28.0
26.4
23.2
7/20/11
heated gas
8
Heated BOC
630
-2.946
0.007
-0.914
0.012
13.78
4.744
0.007
0.007
0.007
0.018
7/20/11
standard
8
Carrara Marble
638
17.90
0.007
-0.277
0.010
38.26
13.52
0.270
0.263
0.344
0.345
0.352
0.017
0.393
129.3
126.8
325.9
7/21/11
heated gas
8
Heated EBOC
672
27.36
0.004
-0.397
0.009
109.0
37.21
-0.018
-0.018
-0.018
0.019
7/21/11
standard
8
TV01
680
11.62
0.005
-0.062
0.008
17.96
6.695
0.598
0.582
0.663
0.665
0.662
0.015
0.739
20.9
19.3
11.5
7/22/2011
heated gas
8
Heated BOC
721
-3.018
0.007
-0.924
0.012
14.08
4.834
-0.002
-0.002
-0.002
0.018
7/22/11
standard
8
Carrara Marble
729
18.04
0.010
-0.244
0.008
39.15
14.34
0.301
0.293
0.374
0.375
0.352
0.016
0.425
113.9
111.6
248.5
7/22/11
sample
8
TM "B" Caliche 1
745
-1.636
0.009
-0.338
0.010
10.65
3.895
0.559
0.545
0.626
0.627
0.017
0.698
29.4
27.7
25.5
7/22/11
sample
8
TM Lenoir 1
753
-0.910
0.005
-0.377
0.016
7.879
2.484
0.508
0.494
0.575
0.576
0.021
0.643
41.9
40.1
47.9
7/22/11
sample
8
TMA3-2
761
-1.084
0.008
-0.315
0.010
10.62
4.151
0.572
0.557
0.638
0.639
0.016
0.711
26.5
24.9
20.6
7/23/2011
heated gas
8
Heated EBOC
778
28.82
0.007
-0.341
0.008
114.7
39.70
0.011
0.011
0.011
0.019
7/23/11
standard
8
TV01
786
11.90
0.010
-0.072
0.006
18.77
7.183
0.583
0.568
0.649
0.650
0.662
0.013
0.723
24.1
22.5
16.7
7/23/11
heated gas
8
Heated BOC
810
-3.033
0.006
-0.931
0.009
14.55
5.242
-0.009
-0.008
-0.008
0.017
7/24/11
standard
8
carrrara Marble
842
18.03
0.005
-0.235
0.011
39.36
14.57
0.310
0.302
0.383
0.384
0.352
0.017
0.435
109.5
107.2
230.1
7/24/11
heated gas
8
Heated EBOC
877
29.49
0.008
-0.336
0.011
118.1
41.62
0.004
0.004
0.004
0.020
7/24/11
standard
7
TV01
885
11.40
0.017
-0.066
0.013
17.68
6.778
0.598
0.582
0.663
0.665
0.662
0.018
0.739
20.9
19.3
11.5
7/25/2011
sample
8
TM "B" Caliche
893
-1.806
0.009
-0.305
0.016
11.14
4.571
0.596
0.580
0.661
0.662
0.021
0.736
21.4
19.8
12.3
07/25/11
heated gas
8
Heated EBOC
926
28.71
0.009
-0.350
0.014
116.7
41.43
0.004
0.004
0.004
0.022
Accepted standard values for Caltech
Standard
Caltech
ARF
n
CM05 (UCSC Carrera)
0.371
0.409
7
Carmel Chalk
0.644
0.719
6
Hagit Carrera
0.352
0.403
76
TV01
0.662
0.733
97
NBS-19
0.352
0.384
*Dennis et al. 2011 value, adjusted to .092 acid digestion correction
Heated gas
0
0.027
*Dennis et al., 2011
*These
Δ
47
values were used to converted to the absolute reference frame of Dennis et al., 2011, following the secondary reference frame approach and the accepted values listed above, except for values from SS9 which were converted using the stretched, non-
acid digestion corrected values (samples run at 25°C)