Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published April 14, 2004 | Supplemental Material
Journal Article Open

An Experimentally Derived Model for Stereoselectivity in the Aerobic Oxidative Kinetic Resolution of Secondary Alcohols by (Sparteine)PdCl_2


A model for asymmetric induction in palladium-catalyzed aerobic oxidative kinetic resolution is described. The model is based on coordination complexes and general reactivity trends of the parent (sp)PdCl2 catalyst. The first example of a nonracemic chiral palladium alkoxide complex is presented, and exhibits the subtle steric influences of the C1symmetric ligand sparteine.

Additional Information

© 2004 American Chemical Society. Received 11 November 2003. Published online 18 March 2004. Published in print 1 April 2004. We are grateful to Caltech and the A. P. Sloan Foundation for financial support. We are indebted to Dr. M. W. Day and Mr. L. M. Henling for X-ray crystallographic expertise as well as to Professors J. E. Bercaw, R. H. Grubbs, H. B. Gray, and J. C. Peters and their groups for assistance and helpful discussions.

Attached Files

Supplemental Material - ja039551qsi20031111_080718.cif

Supplemental Material - ja039551qsi20031111_080733.cif

Supplemental Material - ja039551qsi20031111_080746.cif

Supplemental Material - ja039551qsi20031111_080800.cif

Supplemental Material - ja039551qsi20031111_080814.cif

Supplemental Material - ja039551qsi20040226_010836.pdf


Files (1.7 MB)
Name Size Download all
18.9 kB Download
22.8 kB Download
27.6 kB Download
19.2 kB Download
1.6 MB Preview Download
25.2 kB Download

Additional details

August 19, 2023
October 24, 2023