Published August 14, 2012 | Version public
Book Section - Chapter

Chemical Characteristics of Sediments and Seawater

  • 1. ROR icon Institute of Precambrian Geology and Geochronology
  • 2. ROR icon Norwegian Geological Survey
  • 3. ROR icon University of Bergen
  • 4. ROR icon Czech Geological Survey
  • 5. ROR icon Czech University of Life Sciences Prague
  • 6. ROR icon Harvard University
  • 7. ROR icon Indian Institute of Science Bangalore
  • 8. ROR icon University of California, Riverside
  • 9. ROR icon French Research Institute for Exploitation of the Sea
  • 10. ROR icon European Institute for Marine Studies
  • 11. ROR icon University of Chicago
  • 12. ROR icon Institut de Physique du Globe de Paris
  • 13. ROR icon University of Tübingen
  • 14. ROR icon Colorado State University

Abstract

The transition from an anoxic to oxygenated atmosphere was arguably the most dramatic change in the history of the Earth. This "Great Oxidation Event" (Holland 2006) transformed the biogeochemical cycles of the elements by imposing an oxidative step in the cycles, creating strong redox gradients in the terrestrial and marine realms that energised microbial metabolism. Although much past research was focused on establishing when the rise of atmospheric oxygen took place, recognition that substantial mass-independent fraction (MIF) of the sulphur isotopes is restricted to the time interval before 2.45 Ga and requires an anoxic atmosphere (Farquhar et al. 2000, 2007; Mojzsis et al. 2003; Ono et al. 2003; Bekker et al. 2004) argues the atmosphere became permanently oxygenated at this time (Pavlov and Kasting 2002). A false-start to the modern aerobic biosphere and a "whiff" of atmospheric oxygen (Anbar et al. 2007) may have occurred in the latest Archaean, as reflected in a transient enrichment in the redox-sensitive element molybdenum in marine shales and a reduction in the extent of MIF precisely coincident with the peak in Mo and FeS_2 enrichment (Kaufman et al. 2007). Geochemical proxies are imperfect, and an earlier (c. 3 Ga) appearance of atmospheric oxygen is possible (Ohmoto et al. 2006) but disputed (Farquhar et al. 2007; Buick 2008).

Additional Information

© 2013 Springer-Verlag Berlin Heidelberg. First Online: 14 August 2012.

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Identifiers

Eprint ID
87143
DOI
10.1007/978-3-642-29670-3_10
Resolver ID
CaltechAUTHORS:20180615-081536225

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2018-06-15
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Updated
2021-11-15
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Division of Geological and Planetary Sciences (GPS)