Published January 2015 | Version Published
Journal Article Open

Fast temperature spectrometer for samples under extreme conditions

  • 1. ROR icon California Institute of Technology
  • 2. ROR icon Argonne National Laboratory

Abstract

We have developed a multi-wavelength Fast Temperature Readout (FasTeR) spectrometer to capture a sample's transient temperature fluctuations, and reduce uncertainties in melting temperature determination. Without sacrificing accuracy, FasTeR features a fast readout rate (about 100 Hz), high sensitivity, large dynamic range, and a well-constrained focus. Complimenting a charge-coupled device spectrometer, FasTeR consists of an array of photomultiplier tubes and optical dichroic filters. The temperatures determined by FasTeR outside of the vicinity of melting are, generally, in good agreement with results from the charge-coupled device spectrometer. Near melting, FasTeR is capable of capturing transient temperature fluctuations, at least on the order of 300 K/s. A software tool, SIMFaster, is described and has been developed to simulate FasTeR and assess design configurations. FasTeR is especially suitable for temperature determinations that utilize ultra-fast techniques under extreme conditions. Working in parallel with the laser-heated diamond-anvil cell, synchrotron Mössbauer spectroscopy, and X-ray diffraction, we have applied the FasTeR spectrometer to measure the melting temperature of ^(57)Fe_(0.9) Ni_(0.1) at high pressure.

Additional Information

© 2015 AIP Publishing LLC. Received 1 July 2014; accepted 20 December 2014; published online 13 January 2015. We thank G. Shen, V. B. Prakapenka, M. Rivers, Y. Meng, W. Bi, A. Alatas, and B. Chen for useful discussions and help with commissioning of this system. We are grateful to C. A. Murphy for synthesizing the ^(57)Fe_(0.9)Ni_(0.1) sample. We thank the California Institute of Technology and NSF (EAR-1316362) for support of this research, GSE-CARS and HP-CAT for the use of the laser drilling and the ruby fluorescence systems, and an anonymous reviewer for his/her thoughtful and constructive comments. Use of the Advanced Photon Source is supported by the U.S. D.O.E., O.S., O.B.E.S. (DE-AC02-06CH11357). Sector 3 operations are supported in part by COMPRES under NSF Cooperative Agreement EAR 06-49658.

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Additional details

Identifiers

Eprint ID
53877
Resolver ID
CaltechAUTHORS:20150120-113020653

Funding

Caltech
NSF
EAR-1316362
Department of Energy (DOE)
DE-AC02-06CH11357
NSF
EAR 06-49658

Dates

Created
2015-01-20
Created from EPrint's datestamp field
Updated
2021-11-10
Created from EPrint's last_modified field

Caltech Custom Metadata

Caltech groups
Seismological Laboratory, Division of Geological and Planetary Sciences (GPS)