The Enantioselective Tsuji Allylation
The first catalytic enantioselective examples of the Tsuji allylation using enol carbonates and enol silanes are described. The products possess a quaternary stereogenic center and are useful building blocks for synthetic chemistry.
Additional Information© 2004 American Chemical Society. Received August 27, 2004. The authors are grateful to the Fannie and John Hertz Foundation (predoctoral fellowship to D.C.B.), Caltech, the A. P. Sloan Foundation, and Research Corporation for financial support, and E. Kwei for experimental assistance.
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Supplemental Material - ja044812xsi20041008_053737.pdf