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Published February 4, 1983 | public
Journal Article

Stepwise solvation of molecules as studies by picosecond-jet spectroscopy: dynamics and spectra


We report on the stepwise solvated complexes of isoquinoline with water, methanol, and acetone under supersonic jet conditions. Lifetimes, dispersed fluorescence and excitation spectra are presented for different solute-solvent complexes. These studies reveal manifestations of solute-solvent hydrogen-bonding and of excited state hydrogen bond dissociation.

Additional Information

© 1983 Elsevier North-Holland. Received 5 October 1982. This work was supported by grants from the National Science Foundation: CHE8112833 and DMR8105034.

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