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Published August 1985 | public
Journal Article

Extended correlation between O-F bond energies and ^(19)F NMR chemical shifts in fluoroxy compounds


We wish to report now that an extended set of data, including an experimental measurement of Φ in NO_2OF (Φ = 220) together with existing values for F_2O_2 (D_(O-F) = 18 kcal/mol; Φ = 825) and FOH (54 kcal/mol; 21 ppm), confirms the above conclusions but requires an improved correlation to account for the extremely large spans of both parameters.

Additional Information

© 1985 American Chemical Society. Received October 2, 1984. K.O.C. is grateful to the Office of Naval Research for financial support.

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October 23, 2023