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Published March 21, 2008 | Version Published + Supplemental Material + Cover Image
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Sulfur isotope fractionation during incorporation of sulfur nucleophiles into organic compounds

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Abstract

34S enrichment is shown to occur during sulfurization reactions and for the first time conclusively attributed to an isotope equilibrium effect rather than selective addition of 34S enriched nucleophiles.

Additional Information

© Royal Society of Chemistry 2008. Received (in Cambridge, UK) 5th November 2007, Accepted 2nd January 2008. First published as an Advance Article on the web 16th January 2008. The authors wish to thank David Sprinzak (Caltech) for help with MATLAB programing and Alex Sessions (Caltech) and Dmitri Gelman (Hebrew University) for helpful comments and discussions on an earlier version of this paper. Electronic supplementary information (ESI) available: Experimental and molecular modeling procedures, optimized coordinates for all structures, supplementary data for Tables 1–3, GC-MS trace for some of the products. See DOI: 10.1039/b717113g

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Additional details

Identifiers

Eprint ID
10101
Resolver ID
CaltechAUTHORS:AMRcc08

Dates

Created
2008-04-14
Created from EPrint's datestamp field
Updated
2021-11-08
Created from EPrint's last_modified field