Published March 8, 2001
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Journal Article
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Excitation of the symmetry forbidden bending mode in molecular photoionization
Abstract
We present results on the energy dependence of the vibrational branching ratio for the bending mode in CO2 3sigmau-1 photoionization. Specifically, we determine the v+ = (0,1,0)/v+ = (0,0,0) intensity ratio by detecting dispersed fluorescence from the electronically excited photoions. The results exhibit large deviations over a very wide energy range, 18
Additional Information
© 2001 American Institute of Physics. Received 6 October 2000; accepted 19 December 2000. We thank the CAMD staff for their assistance, and EDP acknowledges support from the National Science Foundation (CHE-9616908). This work was also supported in part by the Robert A. Welch Foundation (Houston, Texas) under Grant No. A-1020. We also acknowledge the support of the Texas A&M University Supercomputing Facility. Finally, we wish to acknowledge helpful conversations with Dr. M.G. White of Brookhaven National Laboratory.Attached Files
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- 11036
- Resolver ID
- CaltechAUTHORS:MILjcp01
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2008-06-24Created from EPrint's datestamp field
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2021-11-08Created from EPrint's last_modified field