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Published December 15, 2011 | Supplemental Material
Journal Article Open

H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex


A PNP-pincer iridium dihydride performs the H/D exchange between aromatic substrates and tertiary hydrosilanes and D_(2)O or C_(6)D_(6). Complete incorporation of deuterium into sterically accessible C_(ar)–H and Si–H bonds was observed at a moderate temperature of 80 °C.

Additional Information

© 2011 American Chemical Society. Received: October 28, 2011; Published: December 15, 2011. Generous financial support of this research was provided by BP (MC2 initiative). A.F. thanks the Swiss National Science Foundation for a postdoctoral fellowship.

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