CaltechAUTHORS
Published November 2015 | Version public
Conference Paper Metadata-only

Mechanistic insights into photo-induced, copper-catalyzed alkylations of amines

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Abstract

Photoinduced, copper-catalyzed cross-couplings have emerged as an attractive class of lightdriven transformations to construct carbon-nitrogen bonds in recent years. Despite the broadening scope with respect to coupling partners, the understanding of the operating mechanisms has been limited to date. Herein, a mechanistic investigation of a photoinduced, copper-catalyzed cross-coupling of amines and alkyl halides, including spectroscopic evidence for a copper intermediate, is presented.

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© 2015 American Chemical Society.

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Eprint ID
64949
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CaltechAUTHORS:20160302-081446965

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http://wrm2015.sites.acs.org/ (URL)

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Created
2016-03-02
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Updated
2020-12-10
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