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Published July 20, 1998 | Supplemental Material
Journal Article Open

Neutral Nickel(II)-Based Catalysts for Ethylene Polymerization


Neutral salicylaldiminato Ni(II) complexes have been synthesized, and their structure has been confirmed by an X-ray analysis of complex 4e. These compounds are active catalysts for the polymerization of ethylene under mild conditions in the presence of a phosphine scavenger such as Ni(COD)_2 or B(C_6F_5)_3.

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© 1998 American Chemical Society. Received March 9, 1998. Support has been provided by the National Institute for Standards and Technology (ATP program) and the Cryovac Division of the Sealed Air Corporation. S.F. is grateful to the Alexander von Humboldt-Stiftung for a Feodor Lynen Postdoctoral fellowship. GPC and polymer NMR analyses were provided by Cryovac.

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