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Published April 23, 2007 | Supplemental Material
Journal Article Open

Ruthenium Olefin Metathesis Catalysts Bearing an N-Fluorophenyl-N-Mesityl-Substituted Unsymmetrical N-Heterocyclic Carbene


Two new ruthenium-based olefin metathesis catalysts, each bearing an unsymmetrical N-heterocyclic carbene ligand, have been synthesized and fully characterized. Their catalytic performance has been evaluated in ring-closing metathesis, cross metathesis, and ring-opening metathesis polymerization reactions.

Additional Information

© 2007 American Chemical Society. Received 17 November 2006. Published online 29 March 2007. Published in print 1 April 2007. The authors would like to thank Larry M. Henling and Dr. Michael W. Day for X-ray crystallographic analysis. Smaranda Marinescu and Prof. John E. Bercaw are acknowledged for assistance with line shape analysis. This research was supported in part by a Marie Curie International Fellowship to G.C.V. within the 6th European Community Framework Programme.

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