Published August 19, 2013
| Version Accepted Version + Supplemental Material
Journal Article
Open
Alkene Chemoselectivity in Ruthenium-Catalyzed Z-Selective Olefin Metathesis
Creators
Abstract
Chelated ruthenium catalysts can facilitate highly chemoselective olefin metathesis. Terminal and internal Z olefins reacted selectively to form new Z olefins in the presence of internal E olefins. Chemoselectivity for terminal olefins was also observed over both sterically hindered and electronically deactivated alkenes.
Additional Information
© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: April 2, 2013; Revised: May 10, 2013; Published online: July 5, 2013. This work was financially supported by the NIH (R01GM031332 and N.R.S.A. to J.S.C.: F32GM103002), and the NSF (CHE-1212767). NMR spectra were obtained by instruments supported by the NIH (RR027690). Materia Inc. is acknowledged for the generous donation of metathesis catalysts 1, 2, 5, and 6.Attached Files
Accepted Version - nihms523183.pdf
Supplemental Material - anie_201302724_sm_miscellaneous_information.pdf
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anie_201302724_sm_miscellaneous_information.pdf
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Additional details
Identifiers
- PMCID
- PMC3826562
- Eprint ID
- 41327
- DOI
- 10.1002/anie.201302724
- Resolver ID
- CaltechAUTHORS:20130913-135632034
Funding
- NIH
- R01GM031332
- NIH Postdoctoral Fellowship
- F32GM103002
- NSF
- CHE-1212767
- NIH
- RR027690
Dates
- Created
-
2013-09-16Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field