Published April 1, 1991 | Version Published
Journal Article Open

Mechanistic investigations of nanometer-scale lithography at liquid-covered graphite surfaces

Abstract

Pulse-induced nanometer-scale lithography has been performed on graphite surfaces that were in contact with pure water or other organic liquids. Very reproducible control over the pit diameter was observed in aqueous solutions, and a well-defined voltage threshold (4.0 ± 0.2 V) was also apparent. Near the threshold voltage, 7 Å diameter × 2 Å high protrusions were formed, while larger initial pulse voltages resulted in pits of diameter> ~20 Å.

Additional Information

© 1991 American Institute of Physics. (Received 13 September 1990; accepted 2 January 1991) We acknowledge the Caltech Consortium in Chemistry and Chemical Engineering; Founding Members: E. I. du Pont de Nemours, Eastman Kodak, 3M, and Shell Development Co. and the Joint Services Electronics Program for support of this work, and Dr. A. Moore of Union Carbide for a generous donation of HOPG. J. Jahanmir at QuanScan Inc. is acknowledged for assistance with Z calibration of the piezo using interferometry. The authors also thank M. Dovek and M. Kirk of Stanford University for valuable conversations regarding experimental results in gaseous ambients. This is contribution No. 8201 from the Division of Chemistry and Chemical Engineering at Caltech.

Attached Files

Published - PENapl91b.pdf

Files

PENapl91b.pdf

Files (520.0 kB)

Name Size Download all
md5:31d3236cebd227aa9a9373c15b8aa283
520.0 kB Preview Download

Additional details

Identifiers

Eprint ID
2422
Resolver ID
CaltechAUTHORS:PENapl91b

Funding

Caltech Consortium in Chemistry and Chemical Engineering

Dates

Created
2006-04-03
Created from EPrint's datestamp field
Updated
2023-04-19
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Caltech Division of Chemistry and Chemical Engineering
Other Numbering System Identifier
8201