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Published February 22, 2010 | Supplemental Material
Journal Article Open

Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C−H Activation


η^3-Cyclohexenyl and -indenyl Pt(II) and Pd(II) diimine complexes, which are generated via C−H activation of cyclohexene and indene by Pt and Pd hydroxy dimers, are selectively oxidized by Br_2, Na_2PtCl_6, and CuCl_2 to give halogenated organic products along with well-defined Pd(II) and Pt(II) species.

Additional Information

© 2010 American Chemical Society. Received July 30, 2009. Publication Date (Web): January 15, 2010. We thank Larry Henling and Mike Day for X-ray crystallographic characterization of complexes and BP for financial support through the MC^2 program.

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