Published March 28, 2006 | Version Supplemental Material + Published + Cover Image
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2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters

Abstract

The formation of various alpha-diazo acetoacetic esters can be obtained in a single transformation with good to excellent yields using readily available 2-diazoacetoacetic acid.

Additional Information

© The Royal Society of Chemistry 2006 Received (in Bloomington, IN, USA) 13th December 2005, Accepted 27th January 2006. First published on the web 15th February 2006 The authors gratefully acknowledge the NSF (predoctoral fellowship for E.M.F.), Bristol-Myers Squibb (Graduate Fellowship in Synthetic Organic Chemistry to E.M.F.), AstraZeneca, Boehringer Ingelheim, Johnson & Johnson, Pfizer, Merck, Amgen, Research Corporation, Roche, the Dreyfus Foundation, and GlaxoSmithKline for generous funding. Electronic supplementary information (ESI) available: experimental details and characterization data for all compounds. See DOI: 10.1039/b517719g

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Published - MEYcc06.pdf

Supplemental Material - MEYcc05supp.pdf

Cover Image - MEYcc06diag.gif

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Additional details

Identifiers

Eprint ID
3509
Resolver ID
CaltechAUTHORS:MEYcc06

Funding

NSF Predoctoral Fellowship
Bristol-Myers Squibb
AstraZeneca
Boehringer-Ingelheim
Johnson and Johnson
Pfizer
Merck
Amgen
Research Corporation
Roche
Camille and Henry Dreyfus Foundation
GlaxoSmithKline

Dates

Created
2006-06-11
Created from EPrint's datestamp field
Updated
2021-11-08
Created from EPrint's last_modified field