CaltechAUTHORS
Published January 17, 1986 | Version public
Journal Article Metadata-only

Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy

Creators

  • 1. ROR icon California Institute of Technology
  • 2. ROR icon University of California, Santa Barbara

Abstract

The electronic states of the unsaturated organometallic carbene CrCH_2^+ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, ^6B_1, and ^6A_1 at 0.78 and 0.82 eV respectively, above the ^4B_1 ground state of CrCH_2^+.

Additional Information

© 1986 Published by Elsevier B.V. Received 4 November 1985. Arthur Amos Noyes Laboratory of Chemical Physics Contribution No. 7320. This work was supported by the National Science Foundation under Grants No. CHE-8318041 (WAG), CHE-8020464 (MTB) and CHE-8407857 (JLB). Support from the Shell Development Company (WAG) and the Atlantic Richfield Foundation (MAH graduate fellowship) is gratefully acknowledged. EAC acknowledges a National Science Foundation predoctoral fellowship (1982-1985).

Additional details

Identifiers

Eprint ID
88410
DOI
10.1016/0009-2614(86)80064-1
Resolver ID
CaltechAUTHORS:20180731-152042927

Related works

Describes
10.1016/0009-2614(86)80064-1 (DOI)

Funding

NSF
CHE-8318041
NSF
CHE-8020464
NSF
CHE-8407857
Shell Development Company
Atlantic Richfield Foundation
NSF Predoctoral Fellowship

Dates

Created
2018-07-31
Created from EPrint's datestamp field
Updated
2021-11-16
Created from EPrint's last_modified field

Caltech Custom Metadata

Other Numbering System Name
Arthur Amos Noyes Laboratory of Chemical Physics
Other Numbering System Identifier
7320