Published February 15, 1928 | Version public
Journal Article Open

The Quantum Theory of Quasi-Unimolecular Gas Reactions

Abstract

In the discussion of [Eq.] (1) they assumed that the energy expression for the molecule consisted of a sum of squares of coordinates and momenta, and treated the problem by the methods of classical statistical mechanics. In this paper the former assumption is retained, but we will attempt to indicate the nature of the modifications which must be made when the motions of the molecule are quantized.

Additional Information

Copyright © 1928 by the National Academy of Sciences Communicated January 6, 1928 In conclusion the writer wishes to acknowledge his indebtedness to various members of Gates Chemical Laboratory, especially to Dr. L. S. Kassel who is attacking the same problem from another angle. He is also indebted to Dr. H. C. Ramsperger of Stanford University. [O.K.R. was a] National Research Fellow.

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