Published January 7, 2011 | Version Supplemental Material + Published
Journal Article Open

Rhodium complexes bearing tetradentate diamine-bis(phenolate) ligands

  • 1. ROR icon University of Southern California
  • 2. ROR icon Scripps Research Institute
  • 3. ROR icon California Institute of Technology

Abstract

Using tetradentate, dianionic ligands, several new rhodium complexes have been prepared. Some of these diamine-bis(phenolate) compounds, are active for C–H activation of benzene. These complexes are air and thermally stable. All four complexes were characterized by X-ray diffraction.

Additional Information

© 2011 The Royal Society of Chemistry. Received 11th August 2010, Accepted 20th September 2010. The authors thank Chevron Energy Technology Company, Center for Catalytic Hydrocarbon Functionalization, an Energy Frontier Research Center (DOE DE-SC000-1298) and Scripps Florida for financial Support. The facilities of the Materials and Process Simulation Center used for these studies were provided by DURIP-ARO and DURIP-ONR. The authors thank Muhammed Yousufuddin, Nam Nhat Ho, Irina Tsyba and Professor Bau for X-ray diffraction studies. The authors also thank Mu-Jeng Cheng, Robert J. Nielsen, and Richard J. Staples for helpful discussions.

Attached Files

Published - Liu2011p12830Dalton_Transactions.pdf

Supplemental Material - C0DT00997K.TXT

Supplemental Material - C0DT00997K.pdf

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Additional details

Identifiers

Eprint ID
22704
Resolver ID
CaltechAUTHORS:20110308-083347509

Funding

Chevron Energy Technology Company
DOE DE-SC000-1298
Scripps Florida
Army Research Office (ARO)
Office of Naval Research (ONR)

Dates

Created
2011-03-08
Created from EPrint's datestamp field
Updated
2021-11-09
Created from EPrint's last_modified field