Inorg. Chem., 1998, 37(12), 3007-3012, DOI:10.1021/ic9800738
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Copyright © 1998 American Chemical Society
U
199
American
fiemical
society
Inorganic
uhemistry
Vi!
Fage
jUUI
iviurmer
supplemental
Page
i
100
75
-
50
a
25
Enantiomers
of
[Rh(phen)
2
(NH
3
)
2
3
-25
A
-501
266
44
-38
280
-80
70
-75
V304
-16
14
200
250
300
350
X
[nm]
400
450
500
Figure
IS.
CD
spectra
of
A-[Rh(phen)
2
(NH
3
)
2
]C
3
(dashed
line)
and
A-
[Rh(phen)
2
(NH)
2
]C1
3
(solid
line)
in
acetonitrile/water
1:1.
'a
....-.
A
without
heating
A
after
evaporation
'N
i
. I
(G1998
American
Chemical
Society
Inorganic
Chemistry
V37
Page
3007
Murner
Supplemental
Page
2
150
100
50
50
'
.
00
-1501
250
290
330
370
X
[nm]
Figure
2S.
CD
spectra
of
A-[Rh(bpy)
2
(chrysi)]Cl
3
(solid
line)
and
A-
[Rh(bpy)
2
(chrysi)]Cl
3
(dashed
line)
in
water.
V
199
American
fiemical
society
Inorganic
uhemistry
Vi!
Iage
jUUI
iviumer
Supplementa
IPage
j
10
s.......................
20
sec
...........
..
.......
30
sec
40sec
--
-
Y
10
-
-
1:15
min
1:30
min
min
-
..
..
\
2min~
20
min
-
40
m
ln
--
^--
I
bhr
\-
--
0
10
20
30
Retention
Time
[min]
Figure
3S.
HPLC
traces
for
the
reaction
of
[Rh(phen)(NH)
4
V"
with
I
eq.
9,10-
phenanthrene
quinone
showing
the
clean
conversion
of
the
starting
materials
within
an
hour.
(G1998
American
Chemical
Society
Inorganic
Chemistry
V37
Page
3007
Murner
Supplemental
Page
4
Figure
4S.
HPLC
traces
for
the
reaction
of
A-[Rh(phen)
2
(NH3)2]
with
9,10-
phenanthrene
quinone
illustrating
the
clean
conversion
of
the
starting
materials
also
with
enantiomerically
pure
metal
complex.