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Published June 1, 1987 | Published
Journal Article Open

Catalytic Oxidation of Styrene in the Presence of Square Planar Cobalt(iii) Complexes of Polyanionic Chelating Ligands


Styrene has been catalytically oxidised in the presence of iodosoarenes and square planar cobalt(iii) complexes of polyanionic chelating (PAC) ligands; possible intermediates in these oxygen atom transfer reactions include cobalt(v)-oxo complexes.

Additional Information

© 1987 Royal Society of Chemistry. Received 13th January 1987; Com. 040. We thank the Rohm and Haas Co., the Atlantic Richfield Corporation of America, and the National Science Foundation (Grant CHE-84-06198) for support of this work. S.O. thanks the Japanese Government for support for sabbatical leave from the University of Osaka. T.J.C. is a Dreyfus J. CHEM. SOC., CHEM. COMMUN., 1987 Teacher-Scholar (1986-1990) and an Alfred P. Sloan Research Fellow (19861988). The Chemical Laboratories, California Institute of Technology, Pasadena, CA 91 125, U.S.A. Contribution No. 7354.

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