Published June 1979
| Version public
Journal Article
Nitrogen-15 Nuclear Magnetic Resonance Spectra of Isocyanates, Isothiocyanates and N-Sulfinylamines
Creators
Abstract
The ^(15)N NMR spectra of ten isocyanates, four isothiocyanates, and four N-sulfinylamines have been obtained at the natural-abundance level by high-resolution NMR spectroscopy. The results show that isocyanates and isothiocyanates have ^(15)N chemical shifts over 200 ppm toward higher fields compared to those of N-sulfinylamines. The sensitivity of the ^(15)N shifts in these substances to substituent and electronic effects are discussed.
Additional Information
© 1979 Heyden & Son Ltd. Received 6 June 1978; accepted 21 July 1978. This research was supported by the Public Health Service, Grant No. GM-11072 from the Division of General Medical Sciences, and by the National Science Foundation.Additional details
Identifiers
- Eprint ID
- 61713
- Resolver ID
- CaltechAUTHORS:20151029-113928967
Funding
- U.S. Public Health Service (USPHS)
- GM-11072
- NSF
Dates
- Created
-
2015-10-29Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
Caltech Custom Metadata
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 5795