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Published March 2016 | Version public
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Mechanistic investigation of proton reduction by cobaloximes: Insight from H2 oxidation kinetics

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Abstract

Cobaloximes are a class of earth- abundant proton redn. catalysts that have been known since the 1980's. Previous studies have come to conflicting conclusions about the mechanism of proton redn. by these catalysts, with evidence existing for both a homolytic and heterolytic mechanism. In this work, kinetic anal. of the reverse reaction is used to gain further insight.

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© 2016 American Chemical Society.

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Eprint ID
66650
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CaltechAUTHORS:20160504-105818808

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http://www.acs.org/content/acs/en/meetings/spring-2016.html (URL)

Dates

Created
2016-05-04
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Updated
2019-11-22
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