Published March 4, 2013
| Supplemental Material
Journal Article
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Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins
Abstract
Make it simple! A convenient and general palladium-catalyzed oxidation of internal olefins to ketones is reported. The transformation occurs at room temperature and shows wide substrate scope. Applications to the oxidation of seed-oil derivatives and a bioactive natural product (see scheme) are described, as well as intriguing mechanistic features.
Additional Information
© 2013 Wiley-VCH Verlag GmbH & Co. Issue published online: 27 Feb 2013. Article first published online: 16 Jan 2013. Manuscript Received: 28 Nov 2012. We thank Scott Virgil and the Caltech Center for Catalysis for technical assistance. We gratefully acknowledge financial support from King Abdullah University of Science and Technology Center in Development, King Fahd University of Petroleum and Minerals, the NSF, and the Swiss National Science Foundation for a fellowship to B.M.Attached Files
Supplemental Material - anie_201209541_sm_miscellaneous_information.pdf
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anie_201209541_sm_miscellaneous_information.pdf
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Additional details
- Eprint ID
- 37831
- DOI
- 10.1002/anie.201209541
- Resolver ID
- CaltechAUTHORS:20130409-133125459
- King Abdullah University of Science and Technology (KAUST)
- King Fahd University of Petroleum and Minerals (KFUPM)
- NSF
- Swiss National Science Foundation (SNSF)
- Created
-
2013-04-09Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field