Application of Ion Cyclotron Resonance to the Study of Inelastic Excitation by Low-Energy Electrons

The geometry of the resonance cell employed for ion cyclotron resonance spectroscopy (1-3) is ideally suited for studying inelastic excitation by low-energy electrons. It has been shown that the electron beam traverses a parabolic potential well between the trapping electrodes, the depth of which is approximately half the applied trapping voltage (3,4). Low-energy electrons generated by impact excitation of an atomic or molecular energy level can be trapped in the resonance cell if their final translational energy is insufficient to escape the preset depth of the potential well. These electrons can be drifted from the source of the resonance region by applying the usual static drift field E normal to the primary magnetic field H (4). The electron drift velocity in this crossed field geometry, given by cE/H, is independent of both charge and mass. For typical values of E and H the drift velocity is in the range of 10^1-10^3 cm/sec. In the lower range of accessible drift velocities, the residence time of electrons in the resonance cell approaches 0.1 sec.