Published 2009
| Version Published + Supplemental Material
Journal Article
Open
C-H activation in strongly acidic media. The co-catalytic effect of the reaction medium
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1.
California Institute of Technology
Abstract
Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between Pt^(II)(bpym)Cl_2 (bpym = 2,2'-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.
Additional Information
© 2009 The Royal Society of Chemistry. Received (in Cambridge, UK) 5th December 2008, Accepted 2nd February 2009 First published as an Advance Article on the web 12th March 2009.Attached Files
Published - Ahlquist2009p1702Chem_Commun__Camb_.pdf
Supplemental Material - Ahlquist2009p1702Chem_Commun__Camb__supp.pdf
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Additional details
Identifiers
- Eprint ID
- 14682
- Resolver ID
- CaltechAUTHORS:20090727-152217505
Dates
- Created
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2009-08-04Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field