Published September 1980
| Version Published
Journal Article
Open
Chemisorption of Al and Ga on the GaAs (110) surface
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1.
California Institute of Technology
Abstract
We have studied the initial stages of the chemisorption of Al and Ga on the clean GaAs (110) surface by applying quantum chemical methods to small clusters representing Al or Ga on GaAs (110). These calculations suggest that at smallest coverages Al or Ga bind to a surface Ga atom; for higher coverages Al and the surface Ga interchange positions. We have obtained the binding energy, the chemical shifts of the Ga–3d, As–3d and Al–2p states, and the microscopic dipole associated with chemisorption of Al or Ga on GaAs (110). These results are compared to experimental values and further experiments are suggested.
Additional Information
© 1980 American Vacuum Society. Received 1 April 1980; accepted 20 May 1980. The authors have profitted from numerous discussions with R.S. Bauer and W.E. Spicer about the experimental data. This work was supported in part by a grant from the National Science Foundation (Grant No. DMR74-04965) and in part by the Office of Naval Research (Contract No. N00014-79-C-0797). [C.A.S. was an] IBM Postdoctoral Research Fellow. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 6197.Attached Files
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Additional details
Identifiers
- Eprint ID
- 12172
- Resolver ID
- CaltechAUTHORS:SWAjvst80b
Funding
- National Science Foundation
- DMR74-04965
- Office of Naval Research
- N00014-79-C-0797
Dates
- Created
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2008-10-28Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field