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Published October 25, 2004 | Supplemental Material
Journal Article Open

Insights into the Deactivation of Neutral Nickel Ethylene Polymerization Catalysts in the Presence of Functionalized Olefins


A study on the products of reaction between a neutral nickel(II) olefin polymerization catalyst and methyl acrylate is presented. A deactivation mechanism involving hydrogen transfer from substrate to catalyst is suggested.

Additional Information

© 2004 American Chemical Society. Received 18 August 2004. Published online 29 September 2004. Published in print 1 October 2004. We thank the Rohm and Haas Corp. for funding, Dr. Mona Shahgholi for mass spectral analysis, and Jonathan Owen and Raissa Trend for helpful discussions.

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